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Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer. / Sonina, Alina A.; Koskin, Igor P.; Sherin, Peter S. et al.

In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 74, No. 5, 01.10.2018, p. 450-457.

Research output: Contribution to journalArticlepeer-review

Harvard

Sonina, AA, Koskin, IP, Sherin, PS, Rybalova, TV, Shundrina, IK, Mostovich, EA & Kazantsev, MS 2018, 'Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer', Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, vol. 74, no. 5, pp. 450-457. https://doi.org/10.1107/S2052520618011782

APA

Sonina, A. A., Koskin, I. P., Sherin, P. S., Rybalova, T. V., Shundrina, I. K., Mostovich, E. A., & Kazantsev, M. S. (2018). Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 74(5), 450-457. https://doi.org/10.1107/S2052520618011782

Vancouver

Sonina AA, Koskin IP, Sherin PS, Rybalova TV, Shundrina IK, Mostovich EA et al. Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2018 Oct 1;74(5):450-457. doi: 10.1107/S2052520618011782

Author

Sonina, Alina A. ; Koskin, Igor P. ; Sherin, Peter S. et al. / Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer. In: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2018 ; Vol. 74, No. 5. pp. 450-457.

BibTeX

@article{4ffe665521d549449ec6d73f7391ace5,
title = "Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer",
abstract = "Furan/phenylene co-oligomer single crystals are considered as future materials for organic optoelectronics. Here, the effects of trifluoromethyl substituents on the crystallization, structure and optical properties of furan/phenylene co-oligomer 1,4-bis{5-[4-(trifluoromethyl)phenyl]furan-2-yl}benzene are studied systematically. The solution growth methods and physical vapor transport result in the formation of three polymorphs depending on the growth method and the solvent. Single-crystal X-ray analysis reveals the crystal structures to correspond to H-, J- or mixed aggregates. All obtained crystals exhibit high photoluminescence efficiency and have optical properties which strongly depend on the crystal packing. Variable-temperature X-ray powder diffraction analysis shows the thermal transition of two forms (H- and J-aggregates) into a third one (mixed aggregate). Terminal trifluoromethyl groups induce weak intermolecular interactions which control the crystal packing and optical properties of co-oligomer single crystals.",
keywords = "crystal packing control, furan/phenylene co-oligomer, highly emissive single crystal, polymorphism, MOLECULAR PACKING, FIELD-EFFECT TRANSISTORS, SOLID-STATE, SINGLE-CRYSTALS, PI, FLUORINE, EMISSION, DERIVATIVES, INTERMOLECULAR INTERACTIONS, AGGREGATION",
author = "Sonina, {Alina A.} and Koskin, {Igor P.} and Sherin, {Peter S.} and Rybalova, {Tatyana V.} and Shundrina, {Inna K.} and Mostovich, {Evgeny A.} and Kazantsev, {Maxim S.}",
year = "2018",
month = oct,
day = "1",
doi = "10.1107/S2052520618011782",
language = "English",
volume = "74",
pages = "450--457",
journal = "Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials",
issn = "2052-5192",
publisher = "Wiley-Blackwell",
number = "5",

}

RIS

TY - JOUR

T1 - Crystal packing control of a trifluoromethyl-substituted furan/phenylene co-oligomer

AU - Sonina, Alina A.

AU - Koskin, Igor P.

AU - Sherin, Peter S.

AU - Rybalova, Tatyana V.

AU - Shundrina, Inna K.

AU - Mostovich, Evgeny A.

AU - Kazantsev, Maxim S.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Furan/phenylene co-oligomer single crystals are considered as future materials for organic optoelectronics. Here, the effects of trifluoromethyl substituents on the crystallization, structure and optical properties of furan/phenylene co-oligomer 1,4-bis{5-[4-(trifluoromethyl)phenyl]furan-2-yl}benzene are studied systematically. The solution growth methods and physical vapor transport result in the formation of three polymorphs depending on the growth method and the solvent. Single-crystal X-ray analysis reveals the crystal structures to correspond to H-, J- or mixed aggregates. All obtained crystals exhibit high photoluminescence efficiency and have optical properties which strongly depend on the crystal packing. Variable-temperature X-ray powder diffraction analysis shows the thermal transition of two forms (H- and J-aggregates) into a third one (mixed aggregate). Terminal trifluoromethyl groups induce weak intermolecular interactions which control the crystal packing and optical properties of co-oligomer single crystals.

AB - Furan/phenylene co-oligomer single crystals are considered as future materials for organic optoelectronics. Here, the effects of trifluoromethyl substituents on the crystallization, structure and optical properties of furan/phenylene co-oligomer 1,4-bis{5-[4-(trifluoromethyl)phenyl]furan-2-yl}benzene are studied systematically. The solution growth methods and physical vapor transport result in the formation of three polymorphs depending on the growth method and the solvent. Single-crystal X-ray analysis reveals the crystal structures to correspond to H-, J- or mixed aggregates. All obtained crystals exhibit high photoluminescence efficiency and have optical properties which strongly depend on the crystal packing. Variable-temperature X-ray powder diffraction analysis shows the thermal transition of two forms (H- and J-aggregates) into a third one (mixed aggregate). Terminal trifluoromethyl groups induce weak intermolecular interactions which control the crystal packing and optical properties of co-oligomer single crystals.

KW - crystal packing control

KW - furan/phenylene co-oligomer

KW - highly emissive single crystal

KW - polymorphism

KW - MOLECULAR PACKING

KW - FIELD-EFFECT TRANSISTORS

KW - SOLID-STATE

KW - SINGLE-CRYSTALS

KW - PI

KW - FLUORINE

KW - EMISSION

KW - DERIVATIVES

KW - INTERMOLECULAR INTERACTIONS

KW - AGGREGATION

UR - http://www.scopus.com/inward/record.url?scp=85053542186&partnerID=8YFLogxK

U2 - 10.1107/S2052520618011782

DO - 10.1107/S2052520618011782

M3 - Article

C2 - 30297551

AN - SCOPUS:85053542186

VL - 74

SP - 450

EP - 457

JO - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

JF - Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials

SN - 2052-5192

IS - 5

ER -

ID: 16631906