Standard

Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols. / Fomenko, Iakov S.; Gongola, Marko I.; Shul'pina, Lidia S. et al.

In: Inorganica Chimica Acta, Vol. 565, 121990, 24.05.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Fomenko, IS, Gongola, MI, Shul'pina, LS, Shul'pin, GB, Ikonnikov, NS, Kozlov, YN & Gushchin, AL 2024, 'Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols', Inorganica Chimica Acta, vol. 565, 121990. https://doi.org/10.1016/j.ica.2024.121990

APA

Fomenko, I. S., Gongola, M. I., Shul'pina, L. S., Shul'pin, G. B., Ikonnikov, N. S., Kozlov, Y. N., & Gushchin, A. L. (2024). Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols. Inorganica Chimica Acta, 565, [121990]. https://doi.org/10.1016/j.ica.2024.121990

Vancouver

Fomenko IS, Gongola MI, Shul'pina LS, Shul'pin GB, Ikonnikov NS, Kozlov YN et al. Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols. Inorganica Chimica Acta. 2024 May 24;565:121990. doi: 10.1016/j.ica.2024.121990

Author

Fomenko, Iakov S. ; Gongola, Marko I. ; Shul'pina, Lidia S. et al. / Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols. In: Inorganica Chimica Acta. 2024 ; Vol. 565.

BibTeX

@article{e1dad9f863e24ebdbd64a3d0ad64f429,
title = "Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols",
abstract = "A series of copper(II) complexes of general formula [Cu(R-bian)X2] (X = Cl, Br) (1–5) containing rare and/or hard-to-get BIAN ligands with Ph, 4-OH-Ph, 3-NH2-Py and 3-Py functional groups, have been obtained by a template method. The composition of complexes 1–5 was confirmed by elemental analysis and IR spectroscopy. Complexes 1–5 exhibited high catalytic activity in the oxidation of alkanes and alcohols with peroxides. It has been established that alkyl hydroperoxides are intermediate products in reactions with alkanes. Maximum yield of the oxidation products of cyclohexane attained 31–32 % (complexes 2, 3 and 5). Based on the studies of kinetics and regio- and bond selectivity, it was concluded that hydroxyl radicals play a decisive role in the reaction.",
keywords = "Alcohols, Alkanes, BIAN, Catalysis, Copper complexes, Hydrogen peroxide, Hydroxyl radical, Oxidation, Selectivity, Synthesis, Tert-butyl peroxide",
author = "Fomenko, {Iakov S.} and Gongola, {Marko I.} and Shul'pina, {Lidia S.} and Shul'pin, {Georgiy B.} and Ikonnikov, {Nikolay S.} and Kozlov, {Yuriy N.} and Gushchin, {Artem L.}",
note = "The authors thank the Ministry of Science and Higher Education of the Russian Federation (grants No. 121031700315-2 and 122040500068-0), the Centre of Collective Usage of NIIC SB RAS and the Center for molecular composition studies of INEOS RAS.",
year = "2024",
month = may,
day = "24",
doi = "10.1016/j.ica.2024.121990",
language = "English",
volume = "565",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Copper(II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols

AU - Fomenko, Iakov S.

AU - Gongola, Marko I.

AU - Shul'pina, Lidia S.

AU - Shul'pin, Georgiy B.

AU - Ikonnikov, Nikolay S.

AU - Kozlov, Yuriy N.

AU - Gushchin, Artem L.

N1 - The authors thank the Ministry of Science and Higher Education of the Russian Federation (grants No. 121031700315-2 and 122040500068-0), the Centre of Collective Usage of NIIC SB RAS and the Center for molecular composition studies of INEOS RAS.

PY - 2024/5/24

Y1 - 2024/5/24

N2 - A series of copper(II) complexes of general formula [Cu(R-bian)X2] (X = Cl, Br) (1–5) containing rare and/or hard-to-get BIAN ligands with Ph, 4-OH-Ph, 3-NH2-Py and 3-Py functional groups, have been obtained by a template method. The composition of complexes 1–5 was confirmed by elemental analysis and IR spectroscopy. Complexes 1–5 exhibited high catalytic activity in the oxidation of alkanes and alcohols with peroxides. It has been established that alkyl hydroperoxides are intermediate products in reactions with alkanes. Maximum yield of the oxidation products of cyclohexane attained 31–32 % (complexes 2, 3 and 5). Based on the studies of kinetics and regio- and bond selectivity, it was concluded that hydroxyl radicals play a decisive role in the reaction.

AB - A series of copper(II) complexes of general formula [Cu(R-bian)X2] (X = Cl, Br) (1–5) containing rare and/or hard-to-get BIAN ligands with Ph, 4-OH-Ph, 3-NH2-Py and 3-Py functional groups, have been obtained by a template method. The composition of complexes 1–5 was confirmed by elemental analysis and IR spectroscopy. Complexes 1–5 exhibited high catalytic activity in the oxidation of alkanes and alcohols with peroxides. It has been established that alkyl hydroperoxides are intermediate products in reactions with alkanes. Maximum yield of the oxidation products of cyclohexane attained 31–32 % (complexes 2, 3 and 5). Based on the studies of kinetics and regio- and bond selectivity, it was concluded that hydroxyl radicals play a decisive role in the reaction.

KW - Alcohols

KW - Alkanes

KW - BIAN

KW - Catalysis

KW - Copper complexes

KW - Hydrogen peroxide

KW - Hydroxyl radical

KW - Oxidation

KW - Selectivity

KW - Synthesis

KW - Tert-butyl peroxide

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85186423018&origin=inward&txGid=756cfacba875ccb5a03924a42cb2f6f4

UR - https://www.mendeley.com/catalogue/d262f675-80a1-34b7-bdd8-fb36e493a45d/

U2 - 10.1016/j.ica.2024.121990

DO - 10.1016/j.ica.2024.121990

M3 - Article

VL - 565

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

M1 - 121990

ER -

ID: 60456760