Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co). / Datchuk, R. R.; Grineva, A. A.; Uvarova, M. A. et al.
In: Russian Journal of Inorganic Chemistry, Vol. 64, No. 10, 01.10.2019, p. 1220-1228.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Coordination Polymers of γ,γ'-Dipyridyl and Mononuclear Benzoates M(OOCPh)2[O(H)Me]4 (M = Ni, Co)
AU - Datchuk, R. R.
AU - Grineva, A. A.
AU - Uvarova, M. A.
AU - Yakushev, I. A.
AU - Zubavichus, Ya V.
AU - Nefedov, S. E.
PY - 2019/10/1
Y1 - 2019/10/1
N2 - The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]2[O(H)Me]4 (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)2[O(H)Me]2}n (M = Ni (2), green; Co (3), orange) and {(dipy)2Co2(µ-OOCPh)2(η2-OOCPh)2 ⋅ MeOH}n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy.
AB - The slow diffusion of a γ,γ′-dipyridyl adduct solution in methanol into a methanol solution of the adduct M[(OOCPh]2[O(H)Me]4 (1) at the reagent ratio 1 : 1 and room temperature was found to result in the 1D coordination polymers {dipyM(OOCPh)2[O(H)Me]2}n (M = Ni (2), green; Co (3), orange) and {(dipy)2Co2(µ-OOCPh)2(η2-OOCPh)2 ⋅ MeOH}n (4), pink). Orange polymer 3 was the only product when the initial reagents were diluted three times, and their diffusion was performed at 5°C. Synthesized polymers 2–4 were studied by chemical and X-ray diffraction analyses and IR spectroscopy.
KW - N-donor
KW - nickel and cobalt benzoates
KW - synthesis
KW - X-ray diffraction analysis
KW - METHANOL
KW - METAL-ORGANIC FRAMEWORKS
KW - COPPER(II)
KW - COMPLEXES
KW - ZN(II)
KW - CO(II)
KW - ADDUCT
KW - NI(II)
UR - http://www.scopus.com/inward/record.url?scp=85074763302&partnerID=8YFLogxK
U2 - 10.1134/S0036023619100036
DO - 10.1134/S0036023619100036
M3 - Article
AN - SCOPUS:85074763302
VL - 64
SP - 1220
EP - 1228
JO - Russian Journal of Inorganic Chemistry
JF - Russian Journal of Inorganic Chemistry
SN - 0036-0236
IS - 10
ER -
ID: 25463484