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Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies. / Kuznetsova, Anna A.; Volchek, Victoria V.; Yanshole, Vadim V. et al.

In: Inorganic Chemistry, Vol. 61, No. 37, 19.09.2022, p. 14560-14567.

Research output: Contribution to journal › Article › peer-review

Harvard

Kuznetsova, AA, Volchek, VV, Yanshole, VV, Fedorenko, AD, Kompankov, NB, Kokovkin, VV, Gushchin, AL, Abramov, PA & Sokolov, MN 2022, 'Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies', Inorganic Chemistry, vol. 61, no. 37, pp. 14560-14567. https://doi.org/10.1021/acs.inorgchem.2c01362

APA

Kuznetsova, A. A., Volchek, V. V., Yanshole, V. V., Fedorenko, A. D., Kompankov, N. B., Kokovkin, V. V., Gushchin, A. L., Abramov, P. A., & Sokolov, M. N. (2022). Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies. Inorganic Chemistry, 61(37), 14560-14567. https://doi.org/10.1021/acs.inorgchem.2c01362

Vancouver

Kuznetsova AA, Volchek VV, Yanshole VV, Fedorenko AD, Kompankov NB, Kokovkin VV et al. Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies. Inorganic Chemistry. 2022 Sept 19;61(37):14560-14567. doi: 10.1021/acs.inorgchem.2c01362

Author

Kuznetsova, Anna A. ; Volchek, Victoria V. ; Yanshole, Vadim V. et al. / Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies. In: Inorganic Chemistry. 2022 ; Vol. 61, No. 37. pp. 14560-14567.

BibTeX

@article{5770972602ee4e93b2ecd32daf6564f6,
title = "Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies",
abstract = "Hydrothermal reaction of a macrocyclic inorganic POM cavitand Li17(NH4)21H2[P8W48O184] with [Pt(H2O)2(OH)4] results in coordination of up to six {Pt(H2O)x(OH)4-x} fragments to the internal surface of the polyoxoanion. The product was isolated as K22(NH4)9H3[{Pt(OH)3(H2O)}6P8W48O184]·79H2O (1) and characterized by multiple techniques in the solid state (SCXRD, XRPD, XPS, FTIR, and TGA) and in solution (NMR, ESI-MS, and HPLC-ICP-AES). Electrochemical properties were studied both in solution and as components of the paste electrode. The complex shows electrocatalytic activity in water oxidation.",
author = "Kuznetsova, {Anna A.} and Volchek, {Victoria V.} and Yanshole, {Vadim V.} and Fedorenko, {Anastasiya D.} and Kompankov, {Nikolay B.} and Kokovkin, {Vasily V.} and Gushchin, {Artem L.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2022 American Chemical Society. All rights reserved.",
year = "2022",
month = sep,
day = "19",
doi = "10.1021/acs.inorgchem.2c01362",
language = "English",
volume = "61",
pages = "14560--14567",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "37",

}

RIS

TY - JOUR

T1 - Coordination of Pt(IV) by {P8W48} Macrocyclic Inorganic Cavitand: Structural, Solution, and Electrochemical Studies

AU - Kuznetsova, Anna A.

AU - Volchek, Victoria V.

AU - Yanshole, Vadim V.

AU - Fedorenko, Anastasiya D.

AU - Kompankov, Nikolay B.

AU - Kokovkin, Vasily V.

AU - Gushchin, Artem L.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2022 American Chemical Society. All rights reserved.

PY - 2022/9/19

Y1 - 2022/9/19

N2 - Hydrothermal reaction of a macrocyclic inorganic POM cavitand Li17(NH4)21H2[P8W48O184] with [Pt(H2O)2(OH)4] results in coordination of up to six {Pt(H2O)x(OH)4-x} fragments to the internal surface of the polyoxoanion. The product was isolated as K22(NH4)9H3[{Pt(OH)3(H2O)}6P8W48O184]·79H2O (1) and characterized by multiple techniques in the solid state (SCXRD, XRPD, XPS, FTIR, and TGA) and in solution (NMR, ESI-MS, and HPLC-ICP-AES). Electrochemical properties were studied both in solution and as components of the paste electrode. The complex shows electrocatalytic activity in water oxidation.

AB - Hydrothermal reaction of a macrocyclic inorganic POM cavitand Li17(NH4)21H2[P8W48O184] with [Pt(H2O)2(OH)4] results in coordination of up to six {Pt(H2O)x(OH)4-x} fragments to the internal surface of the polyoxoanion. The product was isolated as K22(NH4)9H3[{Pt(OH)3(H2O)}6P8W48O184]·79H2O (1) and characterized by multiple techniques in the solid state (SCXRD, XRPD, XPS, FTIR, and TGA) and in solution (NMR, ESI-MS, and HPLC-ICP-AES). Electrochemical properties were studied both in solution and as components of the paste electrode. The complex shows electrocatalytic activity in water oxidation.

UR - http://www.scopus.com/inward/record.url?scp=85138452071&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.2c01362

DO - 10.1021/acs.inorgchem.2c01362

M3 - Article

C2 - 36067043

AN - SCOPUS:85138452071

VL - 61

SP - 14560

EP - 14567

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 37

ER -

ID: 38034850