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Coordination Chemistry. Part II : Organometallic Compounds, Catalysis Involving Transition Metal Complexes, and Cluster Compounds. / Sokolov, M. N.; Samsonenko, D. G.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 52, No. 2, 27.05.2026.

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@article{1e86a5f335b748739edff9065ca64a99,

title = "Coordination Chemistry. Part II: Organometallic Compounds, Catalysis Involving Transition Metal Complexes, and Cluster Compounds",

abstract = "This manual contains theoretical material and questions for independent study on selected chapters of coordination chemistry. The material consists of three parts. The first part is devoted to the consideration of organometallic compounds of transition metals as one of the classes of coordination compounds—complexes with a metal–carbon bond. The second part examines the main processes of homogeneous catalysis using coordination compounds. The third part is devoted to the consideration of compounds with metal–metal bonds and cluster compounds, which are divided into two large subclasses—“low-valent” clusters with π-acceptor neutral ligands L, predominantly carbonyl clusters, and “high-valent” clusters containing anionic ligands of type X, such as halides or carboxylates. The concept of isolobal analogies of R. Hoffman is also considered in sufficient detail, which allows for easy establishment of connections between different types of classical complexes, organometallic compounds and clusters.",

keywords = "cluster compounds, coordination compounds, electronic structure, homogeneous catalysis, isolobality concept, organometallic compounds, π-complexes, координационные соединения, электронное строение, металлоорганические соединения, π-комплексы, гомогенный катализ, концепция изолобальности, кластерные соединения",

author = "Sokolov, {M. N.} and Samsonenko, {D. G.}",

note = "Sokolov, M. N. Coordination Chemistry. Part II: Organometallic Compounds, Catalysis Involving Transition Metal Complexes, and Cluster Compounds / M. N. Sokolov, D. G. Samsonenko // Russian Journal of Coordination Chemistry. – 2026. – Vol. 52, No. 2. – P. 1-144. – DOI 10.1134/S107032842560144X. – EDN BECJUH.",

year = "2026",

month = may,

day = "27",

doi = "10.1134/S107032842560144X",

language = "English",

volume = "52",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

issn = "1070-3284",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "2",

}

RIS

TY - JOUR

T1 - Coordination Chemistry. Part II

T2 - Organometallic Compounds, Catalysis Involving Transition Metal Complexes, and Cluster Compounds

AU - Sokolov, M. N.

AU - Samsonenko, D. G.

N1 - Sokolov, M. N. Coordination Chemistry. Part II: Organometallic Compounds, Catalysis Involving Transition Metal Complexes, and Cluster Compounds / M. N. Sokolov, D. G. Samsonenko // Russian Journal of Coordination Chemistry. – 2026. – Vol. 52, No. 2. – P. 1-144. – DOI 10.1134/S107032842560144X. – EDN BECJUH.

PY - 2026/5/27

Y1 - 2026/5/27

N2 - This manual contains theoretical material and questions for independent study on selected chapters of coordination chemistry. The material consists of three parts. The first part is devoted to the consideration of organometallic compounds of transition metals as one of the classes of coordination compounds—complexes with a metal–carbon bond. The second part examines the main processes of homogeneous catalysis using coordination compounds. The third part is devoted to the consideration of compounds with metal–metal bonds and cluster compounds, which are divided into two large subclasses—“low-valent” clusters with π-acceptor neutral ligands L, predominantly carbonyl clusters, and “high-valent” clusters containing anionic ligands of type X, such as halides or carboxylates. The concept of isolobal analogies of R. Hoffman is also considered in sufficient detail, which allows for easy establishment of connections between different types of classical complexes, organometallic compounds and clusters.

AB - This manual contains theoretical material and questions for independent study on selected chapters of coordination chemistry. The material consists of three parts. The first part is devoted to the consideration of organometallic compounds of transition metals as one of the classes of coordination compounds—complexes with a metal–carbon bond. The second part examines the main processes of homogeneous catalysis using coordination compounds. The third part is devoted to the consideration of compounds with metal–metal bonds and cluster compounds, which are divided into two large subclasses—“low-valent” clusters with π-acceptor neutral ligands L, predominantly carbonyl clusters, and “high-valent” clusters containing anionic ligands of type X, such as halides or carboxylates. The concept of isolobal analogies of R. Hoffman is also considered in sufficient detail, which allows for easy establishment of connections between different types of classical complexes, organometallic compounds and clusters.

KW - cluster compounds

KW - coordination compounds

KW - electronic structure

KW - homogeneous catalysis

KW - isolobality concept

KW - organometallic compounds

KW - π-complexes

KW - координационные соединения

KW - электронное строение

KW - металлоорганические соединения

KW - π-комплексы

KW - гомогенный катализ

KW - концепция изолобальности

KW - кластерные соединения

UR - https://www.mendeley.com/catalogue/37b67a85-49f8-3ac9-80da-e8835790c0f9/

UR - https://www.scopus.com/pages/publications/105052710000

UR - https://elibrary.ru/item.asp?id=91272449

U2 - 10.1134/S107032842560144X

DO - 10.1134/S107032842560144X

M3 - Article

VL - 52

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 2

ER -

ID: 85084250

Coordination Chemistry. Part II: Organometallic Compounds, Catalysis Involving Transition Metal Complexes, and Cluster Compounds

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