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Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5. / Kosinov, Nikolay; Wijpkema, Alexandra S.G.; Uslamin, Evgeny et al.

In: Angewandte Chemie - International Edition, Vol. 57, No. 4, 22.01.2018, p. 1016-1020.

Research output: Contribution to journal › Article › peer-review

Harvard

Kosinov, N, Wijpkema, ASG, Uslamin, E, Rohling, R, Coumans, FJAG, Mezari, B, Parastaev, A, Poryvaev, AS, Fedin, MV, Pidko, EA & Hensen, EJM 2018, 'Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5', Angewandte Chemie - International Edition, vol. 57, no. 4, pp. 1016-1020. https://doi.org/10.1002/anie.201711098

APA

Kosinov, N., Wijpkema, A. S. G., Uslamin, E., Rohling, R., Coumans, F. J. A. G., Mezari, B., Parastaev, A., Poryvaev, A. S., Fedin, M. V., Pidko, E. A., & Hensen, E. J. M. (2018). Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5. Angewandte Chemie - International Edition, 57(4), 1016-1020. https://doi.org/10.1002/anie.201711098

Vancouver

Kosinov N, Wijpkema ASG, Uslamin E, Rohling R, Coumans FJAG, Mezari B et al. Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5. Angewandte Chemie - International Edition. 2018 Jan 22;57(4):1016-1020. doi: 10.1002/anie.201711098

Author

Kosinov, Nikolay ; Wijpkema, Alexandra S.G. ; Uslamin, Evgeny et al. / Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5. In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, No. 4. pp. 1016-1020.

BibTeX

@article{20f94620ca8d4abea4be5c0598aafa0d,
title = "Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5",
abstract = "Non-oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite-based Mo/ZSM-5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM-5 are partially reduced single-atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation.",
keywords = "dehydroaromatization, hydrocarbons, methane, Mo/ZSM-5, organocatalysis",
author = "Nikolay Kosinov and Wijpkema, {Alexandra S.G.} and Evgeny Uslamin and Roderigh Rohling and Coumans, {Ferdy J.A.G.} and Brahim Mezari and Alexander Parastaev and Poryvaev, {Artem S.} and Fedin, {Matvey V.} and Pidko, {Evgeny A.} and Hensen, {Emiel J.M.}",
note = "{\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2018",
month = jan,
day = "22",
doi = "10.1002/anie.201711098",
language = "English",
volume = "57",
pages = "1016--1020",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "4",

}

RIS

TY - JOUR

T1 - Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5

AU - Kosinov, Nikolay

AU - Wijpkema, Alexandra S.G.

AU - Uslamin, Evgeny

AU - Rohling, Roderigh

AU - Coumans, Ferdy J.A.G.

AU - Mezari, Brahim

AU - Parastaev, Alexander

AU - Poryvaev, Artem S.

AU - Fedin, Matvey V.

AU - Pidko, Evgeny A.

AU - Hensen, Emiel J.M.

N1 - © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2018/1/22

Y1 - 2018/1/22

N2 - Non-oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite-based Mo/ZSM-5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM-5 are partially reduced single-atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation.

AB - Non-oxidative dehydroaromatization of methane (MDA) is a promising catalytic process for direct valorization of natural gas to liquid hydrocarbons. The application of this reaction in practical technology is hindered by a lack of understanding about the mechanism and nature of the active sites in benchmark zeolite-based Mo/ZSM-5 catalysts, which precludes the solution of problems such as rapid catalyst deactivation. By applying spectroscopy and microscopy, it is shown that the active centers in Mo/ZSM-5 are partially reduced single-atom Mo sites stabilized by the zeolite framework. By combining a pulse reaction technique with isotope labeling of methane, MDA is shown to be governed by a hydrocarbon pool mechanism in which benzene is derived from secondary reactions of confined polyaromatic carbon species with the initial products of methane activation.

KW - dehydroaromatization

KW - hydrocarbons

KW - methane

KW - Mo/ZSM-5

KW - organocatalysis

UR - http://www.scopus.com/inward/record.url?scp=85039059826&partnerID=8YFLogxK

U2 - 10.1002/anie.201711098

DO - 10.1002/anie.201711098

M3 - Article

C2 - 29181863

AN - SCOPUS:85039059826

VL - 57

SP - 1016

EP - 1020

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 4

ER -

ID: 9265658