Standard

Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid. / Kazakova, Mariya A.; Selyutin, Alexander G.; Ishchenko, Arcady V. et al.

In: International Journal of Hydrogen Energy, Vol. 45, No. 38, 31.07.2020, p. 19420-19430.

Research output: Contribution to journal › Article › peer-review

Harvard

Kazakova, MA, Selyutin, AG, Ishchenko, AV, Lisitsyn, AS, Koltunov, KY & Sobolev, VI 2020, 'Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid', International Journal of Hydrogen Energy, vol. 45, no. 38, pp. 19420-19430. https://doi.org/10.1016/j.ijhydene.2020.05.127

APA

Kazakova, M. A., Selyutin, A. G., Ishchenko, A. V., Lisitsyn, A. S., Koltunov, K. Y., & Sobolev, V. I. (2020). Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid. International Journal of Hydrogen Energy, 45(38), 19420-19430. https://doi.org/10.1016/j.ijhydene.2020.05.127

Vancouver

Kazakova MA, Selyutin AG, Ishchenko AV, Lisitsyn AS, Koltunov KY, Sobolev VI. Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid. International Journal of Hydrogen Energy. 2020 Jul 31;45(38):19420-19430. Epub 2020 Jun 7. doi: 10.1016/j.ijhydene.2020.05.127

Author

Kazakova, Mariya A. ; Selyutin, Alexander G. ; Ishchenko, Arcady V. et al. / Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid. In: International Journal of Hydrogen Energy. 2020 ; Vol. 45, No. 38. pp. 19420-19430.

BibTeX

@article{d36b4b0eda54458889a47eb7fd3507a3,
title = "Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid",
abstract = "Formic acid is well-recognized as safe and convenient hydrogen carrier. Development of active and cost-effective catalysts for formic acid to hydrogen conversion is important problem of hydrogen energy field. Herein, we report on new Co catalysts supported on oxidized multi-walled carbon nanotubes (MWCNTs), which demonstrate high efficiency in the gas-phase formic acid decomposition affording molecular hydrogen. Various parameters of the catalysts, Co loading, MWCNTs structure, and nanotubes treatment conditions, have been investigated in terms of their influence on the catalytic properties. The catalysts morphology has been characterized with a set of physicochemical methods. It is found that the catalytic activity of Co particles depends on their electronic state and location on the support. Co species located inside the MWCNTs channels are less active than Co species stabilized on the outer surface. An increase in the content of Co nanoparticles on the MWCNT outer surface leads to a higher catalytic activity.",
keywords = "Co catalyst, Formic acid, Hydrogen production, Multi-walled carbon nanotubes",
author = "Kazakova, {Mariya A.} and Selyutin, {Alexander G.} and Ishchenko, {Arcady V.} and Lisitsyn, {Alexander S.} and Koltunov, {Konstantin Yu} and Sobolev, {Vladimir I.}",
year = "2020",
month = jul,
day = "31",
doi = "10.1016/j.ijhydene.2020.05.127",
language = "English",
volume = "45",
pages = "19420--19430",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
number = "38",

}

RIS

TY - JOUR

T1 - Co/multi-walled carbon nanotubes as highly efficient catalytic nanoreactor for hydrogen production from formic acid

AU - Kazakova, Mariya A.

AU - Selyutin, Alexander G.

AU - Ishchenko, Arcady V.

AU - Lisitsyn, Alexander S.

AU - Koltunov, Konstantin Yu

AU - Sobolev, Vladimir I.

PY - 2020/7/31

Y1 - 2020/7/31

N2 - Formic acid is well-recognized as safe and convenient hydrogen carrier. Development of active and cost-effective catalysts for formic acid to hydrogen conversion is important problem of hydrogen energy field. Herein, we report on new Co catalysts supported on oxidized multi-walled carbon nanotubes (MWCNTs), which demonstrate high efficiency in the gas-phase formic acid decomposition affording molecular hydrogen. Various parameters of the catalysts, Co loading, MWCNTs structure, and nanotubes treatment conditions, have been investigated in terms of their influence on the catalytic properties. The catalysts morphology has been characterized with a set of physicochemical methods. It is found that the catalytic activity of Co particles depends on their electronic state and location on the support. Co species located inside the MWCNTs channels are less active than Co species stabilized on the outer surface. An increase in the content of Co nanoparticles on the MWCNT outer surface leads to a higher catalytic activity.

AB - Formic acid is well-recognized as safe and convenient hydrogen carrier. Development of active and cost-effective catalysts for formic acid to hydrogen conversion is important problem of hydrogen energy field. Herein, we report on new Co catalysts supported on oxidized multi-walled carbon nanotubes (MWCNTs), which demonstrate high efficiency in the gas-phase formic acid decomposition affording molecular hydrogen. Various parameters of the catalysts, Co loading, MWCNTs structure, and nanotubes treatment conditions, have been investigated in terms of their influence on the catalytic properties. The catalysts morphology has been characterized with a set of physicochemical methods. It is found that the catalytic activity of Co particles depends on their electronic state and location on the support. Co species located inside the MWCNTs channels are less active than Co species stabilized on the outer surface. An increase in the content of Co nanoparticles on the MWCNT outer surface leads to a higher catalytic activity.

KW - Co catalyst

KW - Formic acid

KW - Hydrogen production

KW - Multi-walled carbon nanotubes

UR - http://www.scopus.com/inward/record.url?scp=85085993730&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2020.05.127

DO - 10.1016/j.ijhydene.2020.05.127

M3 - Article

AN - SCOPUS:85085993730

VL - 45

SP - 19420

EP - 19430

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 38

ER -

ID: 24470706