Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers

Standard

Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers. / Bagryantseva, I. N.; Kungurtsev, Yu E.; Dormidonova, D. O. et al.

In: Russian Journal of Electrochemistry, Vol. 58, No. 7, 07.2022, p. 611-616.

Research output: Contribution to journal › Article › peer-review

Harvard

Bagryantseva, IN, Kungurtsev, YE, Dormidonova, DO & Ponomareva, VG 2022, 'Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers', Russian Journal of Electrochemistry, vol. 58, no. 7, pp. 611-616. https://doi.org/10.1134/S1023193522070059

APA

Bagryantseva, I. N., Kungurtsev, Y. E., Dormidonova, D. O., & Ponomareva, V. G. (2022). Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers. Russian Journal of Electrochemistry, 58(7), 611-616. https://doi.org/10.1134/S1023193522070059

Vancouver

Bagryantseva IN, Kungurtsev YE, Dormidonova DO, Ponomareva VG. Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers. Russian Journal of Electrochemistry. 2022 Jul;58(7):611-616. doi: 10.1134/S1023193522070059

Author

Bagryantseva, I. N. ; Kungurtsev, Yu E. ; Dormidonova, D. O. et al. / Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers. In: Russian Journal of Electrochemistry. 2022 ; Vol. 58, No. 7. pp. 611-616.

BibTeX

@article{4e943e060bfc4166bdd86caa0f4115dc,

title = "Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers",

abstract = "A comparative study of electrotransport and mechanical properties in the system (1 – x)CsH2PO4–x fluoropolymer (x = 0–0.25 mass fraction) is carried out. As the polymeric additive, ultradispersed polytetrafluoroethylene Forum, a copolymer of polyvinylidene fluoride and hexafluoropropylene, and a copolymer of tetrafluoroethylene and polyvinylidene fluoride are studied. It is shown that the fluoropolymers serve as the chemically inert and thermally stable matrix for CsH2PO4. In these polymer systems, the protonic conductivity is lower as compared with CsH2PO4 as a result of the conductor–insulator percolation effect. However, the improvement of mechanical and hydrophobic properties makes the composites more promising as compared with the pure salt CsH2PO4.",

keywords = "cesium dihydrogen phosphate, fluoropolymers, protonic conductivity, solid electrolytes",

author = "Bagryantseva, {I. N.} and Kungurtsev, {Yu E.} and Dormidonova, {D. O.} and Ponomareva, {V. G.}",

note = "Funding Information: This study was supported by the Russian Scientific Foundation (grant no. 21-73-00298). Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = jul,

doi = "10.1134/S1023193522070059",

language = "English",

volume = "58",

pages = "611--616",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "Maik Nauka-Interperiodica Publishing",

number = "7",

}

RIS

TY - JOUR

T1 - Composite Electrolytes Based on Cesium Dihydrogen Phosphate and Fluropolymers

AU - Bagryantseva, I. N.

AU - Kungurtsev, Yu E.

AU - Dormidonova, D. O.

AU - Ponomareva, V. G.

PY - 2022/7

Y1 - 2022/7

N2 - A comparative study of electrotransport and mechanical properties in the system (1 – x)CsH2PO4–x fluoropolymer (x = 0–0.25 mass fraction) is carried out. As the polymeric additive, ultradispersed polytetrafluoroethylene Forum, a copolymer of polyvinylidene fluoride and hexafluoropropylene, and a copolymer of tetrafluoroethylene and polyvinylidene fluoride are studied. It is shown that the fluoropolymers serve as the chemically inert and thermally stable matrix for CsH2PO4. In these polymer systems, the protonic conductivity is lower as compared with CsH2PO4 as a result of the conductor–insulator percolation effect. However, the improvement of mechanical and hydrophobic properties makes the composites more promising as compared with the pure salt CsH2PO4.

AB - A comparative study of electrotransport and mechanical properties in the system (1 – x)CsH2PO4–x fluoropolymer (x = 0–0.25 mass fraction) is carried out. As the polymeric additive, ultradispersed polytetrafluoroethylene Forum, a copolymer of polyvinylidene fluoride and hexafluoropropylene, and a copolymer of tetrafluoroethylene and polyvinylidene fluoride are studied. It is shown that the fluoropolymers serve as the chemically inert and thermally stable matrix for CsH2PO4. In these polymer systems, the protonic conductivity is lower as compared with CsH2PO4 as a result of the conductor–insulator percolation effect. However, the improvement of mechanical and hydrophobic properties makes the composites more promising as compared with the pure salt CsH2PO4.

KW - cesium dihydrogen phosphate

KW - fluoropolymers

KW - protonic conductivity

KW - solid electrolytes

UR - http://www.scopus.com/inward/record.url?scp=85134385706&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/a2b92beb-dbed-37c5-8076-0f9d51b7dbe4/

U2 - 10.1134/S1023193522070059

DO - 10.1134/S1023193522070059

M3 - Article

AN - SCOPUS:85134385706

VL - 58

SP - 611

EP - 616

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 7

ER -

ID: 36746373