Complex salt [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O as a prospective precursor of Pd–Rh nanoalloys. Cristal structure of Na3[RhOx3]·4H2O

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Complex salt [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O as a prospective precursor of Pd–Rh nanoalloys. Cristal structure of Na3[RhOx3]·4H2O. / Gladysheva, M. V.; Plyusnin, P. E.; Vorobyeva, S. N. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 5, 05.2021, p. 782-793.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{3692c2491bb14a18bc4bbce522e6d3cf,

title = "Complex salt [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O as a prospective precursor of Pd–Rh nanoalloys. Cristal structure of Na3[RhOx3]·4H2O",

abstract = "New complex salts [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O and Na3[RhOx3]·4H2O are prepared. The crystal structures of obtained compounds are determined by XRD. Complex salt [Pd(NH3)4] [Pd(NH3)3NO2][RhOx3]·H2O is studied by powder XRD, IR spectroscopy, and elemental analysis. The state of rhodium(III) in oxalate solutions is studied by NMR. Thermal behavior of [Pd(NH3)4][Pd(NH3)3NO2] [RhOx3]·H2O in various gas atmospheres shows that final thermolysis products in reducing and inert atmospheres are solid solutions Pd1–xRhx.",

keywords = "complex salts, nanoalloys, palladium, rhodium, thermal analysis, X-ray diffraction analysis",

author = "Gladysheva, {M. V.} and Plyusnin, {P. E.} and Vorobyeva, {S. N.} and Komarov, {V. Yu} and Tkachev, {S. V.} and Shubin, {Yu V.} and Korenev, {S. V.}",

note = "Funding Information: The work was funded by the Russian Science Foundation (project No. 16-13-10192). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = may,

doi = "10.1134/S0022476621050140",

language = "English",

volume = "62",

pages = "782--793",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "5",

}

RIS

TY - JOUR

T1 - Complex salt [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O as a prospective precursor of Pd–Rh nanoalloys. Cristal structure of Na3[RhOx3]·4H2O

AU - Gladysheva, M. V.

AU - Plyusnin, P. E.

AU - Vorobyeva, S. N.

AU - Komarov, V. Yu

AU - Tkachev, S. V.

AU - Shubin, Yu V.

AU - Korenev, S. V.

N1 - Funding Information: The work was funded by the Russian Science Foundation (project No. 16-13-10192). Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/5

Y1 - 2021/5

N2 - New complex salts [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O and Na3[RhOx3]·4H2O are prepared. The crystal structures of obtained compounds are determined by XRD. Complex salt [Pd(NH3)4] [Pd(NH3)3NO2][RhOx3]·H2O is studied by powder XRD, IR spectroscopy, and elemental analysis. The state of rhodium(III) in oxalate solutions is studied by NMR. Thermal behavior of [Pd(NH3)4][Pd(NH3)3NO2] [RhOx3]·H2O in various gas atmospheres shows that final thermolysis products in reducing and inert atmospheres are solid solutions Pd1–xRhx.

AB - New complex salts [Pd(NH3)4][Pd(NH3)3NO2][RhOx3]·H2O and Na3[RhOx3]·4H2O are prepared. The crystal structures of obtained compounds are determined by XRD. Complex salt [Pd(NH3)4] [Pd(NH3)3NO2][RhOx3]·H2O is studied by powder XRD, IR spectroscopy, and elemental analysis. The state of rhodium(III) in oxalate solutions is studied by NMR. Thermal behavior of [Pd(NH3)4][Pd(NH3)3NO2] [RhOx3]·H2O in various gas atmospheres shows that final thermolysis products in reducing and inert atmospheres are solid solutions Pd1–xRhx.

KW - complex salts

KW - nanoalloys

KW - palladium

KW - rhodium

KW - thermal analysis

KW - X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=85108105369&partnerID=8YFLogxK

U2 - 10.1134/S0022476621050140

DO - 10.1134/S0022476621050140

M3 - Article

AN - SCOPUS:85108105369

VL - 62

SP - 782

EP - 793

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 28873590