Comparative study of gasoline, diesel and biodiesel autothermal reforming over Rh-based FeCrAl-supported composite catalyst

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Comparative study of gasoline, diesel and biodiesel autothermal reforming over Rh-based FeCrAl-supported composite catalyst. / Potemkin, D. I.; Rogozhnikov, V. N.; Ruban, N. V. et al.

In: International Journal of Hydrogen Energy, Vol. 45, No. 49, 02.10.2020, p. 26197-26205.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{1eb8af1a3df74713abfd8d6bcc795b41,

title = "Comparative study of gasoline, diesel and biodiesel autothermal reforming over Rh-based FeCrAl-supported composite catalyst",

abstract = "Catalytic autothermal reforming (ATR) of a number of hydrocarbon fuels was studied over composite RhCZ-S catalyst (0.24 wt% Rh supported on structured Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl carrier). Iso-octane and n-hexadecane as model compounds of gasoline and diesel fuel, respectively, showed similar properties in ATR process, indicating weak influence of molecular weight and branching degree of liquid alkanes on catalyst performance. Biodiesel ATR characteristics were similar to those of n-hexadecane ATR, as the utilized biodiesel predominantly contained alkanes, being products of fatty acid tail fragments hydrogenation. Even in the case of gasoline ATR, sufficient amount of monoaromatics did not influence a lot on the catalyst performance. Diesel ATR showed rather different situation: the catalyst tended to lose activity due to coking, and incomplete fuel conversion was observed. Analysis of unreacted fuel revealed bi- and polyaromatic compounds (mainly naphtalenes and antracenes) were difficult to convert.",

keywords = "Autothermal reforming, Biodiesel, Diesel, Gasoline, Structured support, Synthesis gas, START-UP, SYNGAS PRODUCTION, STEAM, FUEL-CELL SYSTEMS, GAS SHIFT REACTOR, JET FUELS, SOLAR, HYDROGEN-PRODUCTION, N-DODECANE, PARTIAL OXIDATION",

author = "Potemkin, {D. I.} and Rogozhnikov, {V. N.} and Ruban, {N. V.} and Shilov, {V. A.} and Simonov, {P. A.} and Shashkov, {M. V.} and Sobyanin, {V. A.} and Snytnikov, {P. V.}",

year = "2020",

month = oct,

day = "2",

doi = "10.1016/j.ijhydene.2020.01.076",

language = "English",

volume = "45",

pages = "26197--26205",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

number = "49",

}

RIS

TY - JOUR

T1 - Comparative study of gasoline, diesel and biodiesel autothermal reforming over Rh-based FeCrAl-supported composite catalyst

AU - Potemkin, D. I.

AU - Rogozhnikov, V. N.

AU - Ruban, N. V.

AU - Shilov, V. A.

AU - Simonov, P. A.

AU - Shashkov, M. V.

AU - Sobyanin, V. A.

AU - Snytnikov, P. V.

PY - 2020/10/2

Y1 - 2020/10/2

N2 - Catalytic autothermal reforming (ATR) of a number of hydrocarbon fuels was studied over composite RhCZ-S catalyst (0.24 wt% Rh supported on structured Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl carrier). Iso-octane and n-hexadecane as model compounds of gasoline and diesel fuel, respectively, showed similar properties in ATR process, indicating weak influence of molecular weight and branching degree of liquid alkanes on catalyst performance. Biodiesel ATR characteristics were similar to those of n-hexadecane ATR, as the utilized biodiesel predominantly contained alkanes, being products of fatty acid tail fragments hydrogenation. Even in the case of gasoline ATR, sufficient amount of monoaromatics did not influence a lot on the catalyst performance. Diesel ATR showed rather different situation: the catalyst tended to lose activity due to coking, and incomplete fuel conversion was observed. Analysis of unreacted fuel revealed bi- and polyaromatic compounds (mainly naphtalenes and antracenes) were difficult to convert.

AB - Catalytic autothermal reforming (ATR) of a number of hydrocarbon fuels was studied over composite RhCZ-S catalyst (0.24 wt% Rh supported on structured Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl carrier). Iso-octane and n-hexadecane as model compounds of gasoline and diesel fuel, respectively, showed similar properties in ATR process, indicating weak influence of molecular weight and branching degree of liquid alkanes on catalyst performance. Biodiesel ATR characteristics were similar to those of n-hexadecane ATR, as the utilized biodiesel predominantly contained alkanes, being products of fatty acid tail fragments hydrogenation. Even in the case of gasoline ATR, sufficient amount of monoaromatics did not influence a lot on the catalyst performance. Diesel ATR showed rather different situation: the catalyst tended to lose activity due to coking, and incomplete fuel conversion was observed. Analysis of unreacted fuel revealed bi- and polyaromatic compounds (mainly naphtalenes and antracenes) were difficult to convert.

KW - Autothermal reforming

KW - Biodiesel

KW - Diesel

KW - Gasoline

KW - Structured support

KW - Synthesis gas

KW - START-UP

KW - SYNGAS PRODUCTION

KW - STEAM

KW - FUEL-CELL SYSTEMS

KW - GAS SHIFT REACTOR

KW - JET FUELS

KW - SOLAR

KW - HYDROGEN-PRODUCTION

KW - N-DODECANE

KW - PARTIAL OXIDATION

UR - http://www.scopus.com/inward/record.url?scp=85079534514&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2020.01.076

DO - 10.1016/j.ijhydene.2020.01.076

M3 - Article

AN - SCOPUS:85079534514

VL - 45

SP - 26197

EP - 26205

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 49

ER -

ID: 23472723