Research output: Contribution to journal › Article › peer-review
Chirality-Dependent Growth of Self-Assembled Diphenylalanine Microtubes. / Zelenovskiy, Pavel S.; Nuraeva, Alla S.; Kopyl, Svitlana et al.
In: Crystal Growth and Design, Vol. 19, No. 11, 06.11.2019, p. 6414-6421.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Chirality-Dependent Growth of Self-Assembled Diphenylalanine Microtubes
AU - Zelenovskiy, Pavel S.
AU - Nuraeva, Alla S.
AU - Kopyl, Svitlana
AU - Arkhipov, Sergey G.
AU - Vasilev, Semen G.
AU - Bystrov, Vladimir S.
AU - Gruzdev, Dmitry A.
AU - Waliczek, Mateusz
AU - Svitlyk, Volodymyr
AU - Shur, Vladimir Ya
AU - Mafra, Luís
AU - Kholkin, Andrei L.
N1 - Publisher Copyright: © 2019 American Chemical Society. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2019/11/6
Y1 - 2019/11/6
N2 - The difference in the crystal structure and growth kinetics of microtubes formed from l- and d-enantiomers of diphenylalanine dipeptide is investigated both experimentally and theoretically by computer simulation. The microtubes of l- and d-enantiomers grown simultaneously and under identical experimental conditions possess different crystallographic space groups, have essential difference in sizes, and demonstrate different growth kinetics. Computer simulation by molecular mechanics methods revealed a fundamental difference in the interaction between structural units of microtubes of different chiralities. A model describing chirality-dependent growth of microtubes is proposed.
AB - The difference in the crystal structure and growth kinetics of microtubes formed from l- and d-enantiomers of diphenylalanine dipeptide is investigated both experimentally and theoretically by computer simulation. The microtubes of l- and d-enantiomers grown simultaneously and under identical experimental conditions possess different crystallographic space groups, have essential difference in sizes, and demonstrate different growth kinetics. Computer simulation by molecular mechanics methods revealed a fundamental difference in the interaction between structural units of microtubes of different chiralities. A model describing chirality-dependent growth of microtubes is proposed.
KW - PEPTIDE NANOTUBES
KW - SPIN SELECTIVITY
KW - PHYSICAL-PROPERTIES
KW - ENANTIOMERS
KW - MOLECULES
UR - http://www.scopus.com/inward/record.url?scp=85067931289&partnerID=8YFLogxK
U2 - 10.1021/acs.cgd.9b00884
DO - 10.1021/acs.cgd.9b00884
M3 - Article
AN - SCOPUS:85067931289
VL - 19
SP - 6414
EP - 6421
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 11
ER -
ID: 22366385