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Chiral Manganese Aminopyridine Complexes : The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2. / Ottenbacher, Roman V.; Talsi, Evgenii P.; Bryliakov, Konstantin P.

In: Chemical Record, Vol. 18, No. 1, 01.01.2018, p. 78-90.

Research output: Contribution to journal › Article › peer-review

Harvard

Ottenbacher, RV, Talsi, EP & Bryliakov, KP 2018, 'Chiral Manganese Aminopyridine Complexes: The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2', Chemical Record, vol. 18, no. 1, pp. 78-90. https://doi.org/10.1002/tcr.201700032

APA

Ottenbacher, R. V., Talsi, E. P., & Bryliakov, K. P. (2018). Chiral Manganese Aminopyridine Complexes: The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2. Chemical Record, 18(1), 78-90. https://doi.org/10.1002/tcr.201700032

Vancouver

Ottenbacher RV, Talsi EP, Bryliakov KP. Chiral Manganese Aminopyridine Complexes: The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2. Chemical Record. 2018 Jan 1;18(1):78-90. doi: 10.1002/tcr.201700032

Author

Ottenbacher, Roman V. ; Talsi, Evgenii P. ; Bryliakov, Konstantin P. / Chiral Manganese Aminopyridine Complexes : The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2. In: Chemical Record. 2018 ; Vol. 18, No. 1. pp. 78-90.

BibTeX

@article{26bd1ffeb6e443e88722d2a103da92f6,
title = "Chiral Manganese Aminopyridine Complexes: The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2",
abstract = "In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C-H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.",
keywords = "Asymmetric epoxidation, C-H oxidation, Hydrogen peroxide, Manganese, Mechanism, C−H oxidation, asymmetric epoxidation, hydrogen peroxide, mechanism, manganese, UNFUNCTIONALIZED OLEFINS, HIGHLY ENANTIOSELECTIVE SYNTHESIS, NONHEME FE, N-4 LIGANDS, EFFICIENT OXIDATION, ASYMMETRIC EPOXIDATION, C-H OXIDATION, HYDROGEN-PEROXIDE, MN COMPLEXES, ELECTRON-DEFICIENT OLEFINS",
author = "Ottenbacher, {Roman V.} and Talsi, {Evgenii P.} and Bryliakov, {Konstantin P.}",
note = "{\textcopyright} 2018 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2018",
month = jan,
day = "1",
doi = "10.1002/tcr.201700032",
language = "English",
volume = "18",
pages = "78--90",
journal = "Chemical Record",
issn = "1527-8999",
publisher = "John Wiley and Sons Inc.",
number = "1",

}

RIS

TY - JOUR

T1 - Chiral Manganese Aminopyridine Complexes

T2 - The Versatile Catalysts of Chemo- and Stereoselective Oxidations with H2O2

AU - Ottenbacher, Roman V.

AU - Talsi, Evgenii P.

AU - Bryliakov, Konstantin P.

N1 - © 2018 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C-H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.

AB - In the last decade, manganese(II) complexes with N-donor tetradentate aminopyridine ligands emerged as efficient catalysts of enantioselective epoxidation of olefins and direct selective oxidation of C-H groups in complex organic molecules, with environmentally benign oxidant hydrogen peroxide. In this personal account, we summarize the progress of these catalysts with regard to ligands design, structure-reactivity correlations, evaluation of the substrate scope, as well as mechanistic studies, shedding light on the nature of active sites and the mechanisms of selective oxygenations. Several practically promising catalytic syntheses with the aid of Mn aminopyridine catalysts are exemplified.

KW - Asymmetric epoxidation

KW - C-H oxidation

KW - Hydrogen peroxide

KW - Manganese

KW - Mechanism

KW - C−H oxidation

KW - asymmetric epoxidation

KW - hydrogen peroxide

KW - mechanism

KW - manganese

KW - UNFUNCTIONALIZED OLEFINS

KW - HIGHLY ENANTIOSELECTIVE SYNTHESIS

KW - NONHEME FE

KW - N-4 LIGANDS

KW - EFFICIENT OXIDATION

KW - ASYMMETRIC EPOXIDATION

KW - C-H OXIDATION

KW - HYDROGEN-PEROXIDE

KW - MN COMPLEXES

KW - ELECTRON-DEFICIENT OLEFINS

UR - http://www.scopus.com/inward/record.url?scp=85025171244&partnerID=8YFLogxK

U2 - 10.1002/tcr.201700032

DO - 10.1002/tcr.201700032

M3 - Article

C2 - 28707370

AN - SCOPUS:85025171244

VL - 18

SP - 78

EP - 90

JO - Chemical Record

JF - Chemical Record

SN - 1527-8999

IS - 1

ER -

ID: 9048879