Chemiresistive properties of imprinted fluorinated graphene films

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Chemiresistive properties of imprinted fluorinated graphene films. / Sysoev, Vitalii I.; Bulavskiy, Mikhail O.; Pinakov, Dmitry V. et al.

In: Materials, Vol. 13, No. 16, 3538, 11.08.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Sysoev, VI, Bulavskiy, MO, Pinakov, DV, Chekhova, GN, Asanov, IP, Gevko, PN, Bulusheva, LG & Okotrub, AV 2020, 'Chemiresistive properties of imprinted fluorinated graphene films', Materials, vol. 13, no. 16, 3538. https://doi.org/10.3390/MA13163538

APA

Sysoev, V. I., Bulavskiy, M. O., Pinakov, D. V., Chekhova, G. N., Asanov, I. P., Gevko, P. N., Bulusheva, L. G., & Okotrub, A. V. (2020). Chemiresistive properties of imprinted fluorinated graphene films. Materials, 13(16), [3538]. https://doi.org/10.3390/MA13163538

Vancouver

Sysoev VI, Bulavskiy MO, Pinakov DV, Chekhova GN, Asanov IP, Gevko PN et al. Chemiresistive properties of imprinted fluorinated graphene films. Materials. 2020 Aug 11;13(16):3538. doi: 10.3390/MA13163538

Author

Sysoev, Vitalii I. ; Bulavskiy, Mikhail O. ; Pinakov, Dmitry V. et al. / Chemiresistive properties of imprinted fluorinated graphene films. In: Materials. 2020 ; Vol. 13, No. 16.

BibTeX

@article{a3a8c330d73b46389a9f385174f85e06,

title = "Chemiresistive properties of imprinted fluorinated graphene films",

abstract = "The electrical conductivity of graphene materials is strongly sensitive to the surface adsorbates, which makes them an excellent platform for the development of gas sensor devices. Functionalization of the surface of graphene opens up the possibility of adjusting the sensor to a target molecule. Here, we investigated the sensor properties of fluorinated graphene films towards exposure to low concentrations of nitrogen dioxide NO2. The films were produced by liquid-phase exfoliation of fluorinated graphite samples with a composition of CF0.08, CF0.23, and CF0.33. Fluorination of graphite using a BrF3/Br2 mixture at room temperature resulted in the covalent attachment of fluorine to basal carbon atoms, which was confirmed by X-ray photoelectron and Raman spectroscopies. Depending on the fluorination degree, the graphite powders had a different dispersion ability in toluene, which affected an average lateral size and thickness of the flakes. The films obtained from fluorinated graphite CF0.33 showed the highest relative response ca. 43% towards 100 ppm NO2 and the best recovery ca. 37% at room temperature.",

keywords = "Adsorption, Fluorinated graphene, Gas sensor, Nitrogen dioxide, Resistivity, adsorption, OXIDE, AMMONIA, PERFORMANCE, fluorinated graphene, gas sensor, NANOSHEETS, GRAPHITE, FLUOROGRAPHENE, LAYERS, nitrogen dioxide, PLASMA, GAS SENSOR, resistivity",

author = "Sysoev, {Vitalii I.} and Bulavskiy, {Mikhail O.} and Pinakov, {Dmitry V.} and Chekhova, {Galina N.} and Asanov, {Igor P.} and Gevko, {Pavel N.} and Bulusheva, {Lyubov G.} and Okotrub, {Alexander V.}",

year = "2020",

month = aug,

day = "11",

doi = "10.3390/MA13163538",

language = "English",

volume = "13",

journal = "Materials",

issn = "1996-1944",

publisher = "MDPI AG",

number = "16",

}

RIS

TY - JOUR

T1 - Chemiresistive properties of imprinted fluorinated graphene films

AU - Sysoev, Vitalii I.

AU - Bulavskiy, Mikhail O.

AU - Pinakov, Dmitry V.

AU - Chekhova, Galina N.

AU - Asanov, Igor P.

AU - Gevko, Pavel N.

AU - Bulusheva, Lyubov G.

AU - Okotrub, Alexander V.

PY - 2020/8/11

Y1 - 2020/8/11

N2 - The electrical conductivity of graphene materials is strongly sensitive to the surface adsorbates, which makes them an excellent platform for the development of gas sensor devices. Functionalization of the surface of graphene opens up the possibility of adjusting the sensor to a target molecule. Here, we investigated the sensor properties of fluorinated graphene films towards exposure to low concentrations of nitrogen dioxide NO2. The films were produced by liquid-phase exfoliation of fluorinated graphite samples with a composition of CF0.08, CF0.23, and CF0.33. Fluorination of graphite using a BrF3/Br2 mixture at room temperature resulted in the covalent attachment of fluorine to basal carbon atoms, which was confirmed by X-ray photoelectron and Raman spectroscopies. Depending on the fluorination degree, the graphite powders had a different dispersion ability in toluene, which affected an average lateral size and thickness of the flakes. The films obtained from fluorinated graphite CF0.33 showed the highest relative response ca. 43% towards 100 ppm NO2 and the best recovery ca. 37% at room temperature.

AB - The electrical conductivity of graphene materials is strongly sensitive to the surface adsorbates, which makes them an excellent platform for the development of gas sensor devices. Functionalization of the surface of graphene opens up the possibility of adjusting the sensor to a target molecule. Here, we investigated the sensor properties of fluorinated graphene films towards exposure to low concentrations of nitrogen dioxide NO2. The films were produced by liquid-phase exfoliation of fluorinated graphite samples with a composition of CF0.08, CF0.23, and CF0.33. Fluorination of graphite using a BrF3/Br2 mixture at room temperature resulted in the covalent attachment of fluorine to basal carbon atoms, which was confirmed by X-ray photoelectron and Raman spectroscopies. Depending on the fluorination degree, the graphite powders had a different dispersion ability in toluene, which affected an average lateral size and thickness of the flakes. The films obtained from fluorinated graphite CF0.33 showed the highest relative response ca. 43% towards 100 ppm NO2 and the best recovery ca. 37% at room temperature.

KW - Adsorption

KW - Fluorinated graphene

KW - Gas sensor

KW - Nitrogen dioxide

KW - Resistivity

KW - adsorption

KW - OXIDE

KW - AMMONIA

KW - PERFORMANCE

KW - fluorinated graphene

KW - gas sensor

KW - NANOSHEETS

KW - GRAPHITE

KW - FLUOROGRAPHENE

KW - LAYERS

KW - nitrogen dioxide

KW - PLASMA

KW - GAS SENSOR

KW - resistivity

UR - http://www.scopus.com/inward/record.url?scp=85090030318&partnerID=8YFLogxK

U2 - 10.3390/MA13163538

DO - 10.3390/MA13163538

M3 - Article

AN - SCOPUS:85090030318

VL - 13

JO - Materials

JF - Materials

SN - 1996-1944

IS - 16

M1 - 3538

ER -

ID: 25286859