Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal-Organic Frameworks

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Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal-Organic Frameworks. / Kolokolov, Daniil I.; Lim, Dae Woon; Kitagawa, Hiroshi.

In: Chemical Record, Vol. 20, No. 11, 11.2020, p. 1297-1313.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{a5abe53eb9174f13936920f7e55faa18,

title = "Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal-Organic Frameworks",

abstract = "Proton conductivity has been traditionally investigated with various materials such as organic polymers, metal oxides, and other inorganic and organic compounds because of their potential application in the electrochemical devices. In particular, during the last decade, crystalline porous coordination polymers (PCPs) or metal-organic frameworks (MOFs) have received considerable attention in recent years, as solid-state proton conductors (SSPCs). To date, proton-conductive MOFs have achieved high performance in proton conductivity (>10−2 S cm−1) with rational design strategies. In addition, there are dedicated efforts to define the conduction pathway and mechanism using various experimental tools. In this review, we focus on the characterization of proton conductivity and molecular dynamics in hydrated MOFs, with selected examples to provide an understanding of the overall conduction mechanism.",

keywords = "Conduction Mechanism, Metal-Organic Frameworks, Porous Coordination Polymers, Proton Conductivity, Proton Dynamics, TRANSPORT, POROUS COORDINATION POLYMERS, NEUTRON-SCATTERING, STATE, DIFFUSION, MOFS",

author = "Kolokolov, {Daniil I.} and Lim, {Dae Woon} and Hiroshi Kitagawa",

year = "2020",

month = nov,

doi = "10.1002/tcr.202000072",

language = "English",

volume = "20",

pages = "1297--1313",

journal = "Chemical Record",

issn = "1527-8999",

publisher = "John Wiley and Sons Inc.",

number = "11",

}

RIS

TY - JOUR

T1 - Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal-Organic Frameworks

AU - Kolokolov, Daniil I.

AU - Lim, Dae Woon

AU - Kitagawa, Hiroshi

PY - 2020/11

Y1 - 2020/11

N2 - Proton conductivity has been traditionally investigated with various materials such as organic polymers, metal oxides, and other inorganic and organic compounds because of their potential application in the electrochemical devices. In particular, during the last decade, crystalline porous coordination polymers (PCPs) or metal-organic frameworks (MOFs) have received considerable attention in recent years, as solid-state proton conductors (SSPCs). To date, proton-conductive MOFs have achieved high performance in proton conductivity (>10−2 S cm−1) with rational design strategies. In addition, there are dedicated efforts to define the conduction pathway and mechanism using various experimental tools. In this review, we focus on the characterization of proton conductivity and molecular dynamics in hydrated MOFs, with selected examples to provide an understanding of the overall conduction mechanism.

AB - Proton conductivity has been traditionally investigated with various materials such as organic polymers, metal oxides, and other inorganic and organic compounds because of their potential application in the electrochemical devices. In particular, during the last decade, crystalline porous coordination polymers (PCPs) or metal-organic frameworks (MOFs) have received considerable attention in recent years, as solid-state proton conductors (SSPCs). To date, proton-conductive MOFs have achieved high performance in proton conductivity (>10−2 S cm−1) with rational design strategies. In addition, there are dedicated efforts to define the conduction pathway and mechanism using various experimental tools. In this review, we focus on the characterization of proton conductivity and molecular dynamics in hydrated MOFs, with selected examples to provide an understanding of the overall conduction mechanism.

KW - Conduction Mechanism

KW - Metal-Organic Frameworks

KW - Porous Coordination Polymers

KW - Proton Conductivity

KW - Proton Dynamics

KW - TRANSPORT

KW - POROUS COORDINATION POLYMERS

KW - NEUTRON-SCATTERING

KW - STATE

KW - DIFFUSION

KW - MOFS

UR - http://www.scopus.com/inward/record.url?scp=85091236777&partnerID=8YFLogxK

U2 - 10.1002/tcr.202000072

DO - 10.1002/tcr.202000072

M3 - Article

C2 - 32959508

AN - SCOPUS:85091236777

VL - 20

SP - 1297

EP - 1313

JO - Chemical Record

JF - Chemical Record

SN - 1527-8999

IS - 11

ER -

ID: 25680414