Research output: Contribution to journal › Article › peer-review
Changes in the crystallinity degree of starch having different types of crystal structure after mechanical pretreatment. / Dome, Karina; Podgorbunskikh, Ekaterina; Bychkov, Aleksey et al.
In: Polymers, Vol. 12, No. 3, 641, 12.03.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Changes in the crystallinity degree of starch having different types of crystal structure after mechanical pretreatment
AU - Dome, Karina
AU - Podgorbunskikh, Ekaterina
AU - Bychkov, Aleksey
AU - Lomovsky, Oleg
N1 - Publisher Copyright: © 2020 by the authors. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/3/12
Y1 - 2020/3/12
N2 - This paper examines the effect of mechanical activation on the amorphization of starch having different types of crystalline structure (A-type corn starch; B-type potato starch; and C-type tapioca starch). Structural properties of the starches were studied by X-ray diffraction analysis. Mechanical activation in a planetary ball mill reduces the degree of crystallinity in proportion to pretreatment duration. C-type tapioca starch was found to have the highest degree of crystallinity. Energy consumed to achieve complete amorphization of the starches having different types of crystalline structure was measured. The kinetic parameters of the process (the effective rate constants) were determined. The rate constant and the strongest decline in the crystallinity degree after mechanical activation change in the following series: C-type starch, A-type starch, and B-type starch.
AB - This paper examines the effect of mechanical activation on the amorphization of starch having different types of crystalline structure (A-type corn starch; B-type potato starch; and C-type tapioca starch). Structural properties of the starches were studied by X-ray diffraction analysis. Mechanical activation in a planetary ball mill reduces the degree of crystallinity in proportion to pretreatment duration. C-type tapioca starch was found to have the highest degree of crystallinity. Energy consumed to achieve complete amorphization of the starches having different types of crystalline structure was measured. The kinetic parameters of the process (the effective rate constants) were determined. The rate constant and the strongest decline in the crystallinity degree after mechanical activation change in the following series: C-type starch, A-type starch, and B-type starch.
KW - Amorphization
KW - Crystalline structure of starch
KW - Crystallinity degree
KW - Energy expenditure
KW - Mechanical activation
KW - Rate constant
KW - mechanical activation
KW - amorphization
KW - crystalline structure of starch
KW - ENERGY-CONSUMPTION
KW - energy expenditure
KW - CASSAVA STARCH
KW - crystallinity degree
KW - PHYSICOCHEMICAL PROPERTIES
KW - rate constant
KW - CELLULOSE
UR - http://www.scopus.com/inward/record.url?scp=85082722232&partnerID=8YFLogxK
U2 - 10.3390/polym12030641
DO - 10.3390/polym12030641
M3 - Article
C2 - 32178224
AN - SCOPUS:85082722232
VL - 12
JO - Polymers
JF - Polymers
SN - 2073-4360
IS - 3
M1 - 641
ER -
ID: 23951092