Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring

Standard

Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring. / Petrov, Pavel A.; Filippova, Elizaveta A.; Eltsov, Ilia V. et al.

In: Journal of Organometallic Chemistry, Vol. 949, 121946, 15.09.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Filippova, EA, Eltsov, IV, Sukhikh, TS, Piskunov, AV & Sokolov, MN 2021, 'Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring', Journal of Organometallic Chemistry, vol. 949, 121946. https://doi.org/10.1016/j.jorganchem.2021.121946

APA

Petrov, P. A., Filippova, E. A., Eltsov, I. V., Sukhikh, T. S., Piskunov, A. V., & Sokolov, M. N. (2021). Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring. Journal of Organometallic Chemistry, 949, [121946]. https://doi.org/10.1016/j.jorganchem.2021.121946

Vancouver

Petrov PA, Filippova EA, Eltsov IV, Sukhikh TS, Piskunov AV, Sokolov MN. Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring. Journal of Organometallic Chemistry. 2021 Sept 15;949:121946. doi: 10.1016/j.jorganchem.2021.121946

Author

Petrov, Pavel A. ; Filippova, Elizaveta A. ; Eltsov, Ilia V. et al. / Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring. In: Journal of Organometallic Chemistry. 2021 ; Vol. 949.

BibTeX

@article{7dca3ba21d624c38b2aeb227835dadf5,

title = "Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring",

abstract = "Reaction of [Cp'2ZrMe2] (Cp' = η5-tBuC5H4) with 3,6-di-tert-butylcatechol (H2Cat36) leads to complex [Cp'2ZrCat36] (1). Analogous reaction of [Cp'2ZrMe2] with 3,6-di-tert-butyl-o-benzoquinone (Q36) results in migration of the methyl group from metal to the C6-ring and formation of a complex of 3-tert-butyl-6-methyl-catecholate [Cp'2ZrCat36Me] (2). Both products were characterized with single crystal X-ray diffraction and NMR spectroscopy.",

keywords = "C–C Bond activation, NMR, Quinones, X-ray diffraction analysis, Zirconium",

author = "Petrov, {Pavel A.} and Filippova, {Elizaveta A.} and Eltsov, {Ilia V.} and Sukhikh, {Taisiya S.} and Piskunov, {Alexandr V.} and Sokolov, {Maxim N.}",

note = "Funding Information: We thank Russian Academy of Sciences for funding (budgetary program V.44.4.5 ). Publisher Copyright: {\textcopyright} 2021 Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = sep,

day = "15",

doi = "10.1016/j.jorganchem.2021.121946",

language = "English",

volume = "949",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Catecholate derivatives of zirconocene: Facile methylation of a catecholate ring

AU - Petrov, Pavel A.

AU - Filippova, Elizaveta A.

AU - Eltsov, Ilia V.

AU - Sukhikh, Taisiya S.

AU - Piskunov, Alexandr V.

AU - Sokolov, Maxim N.

PY - 2021/9/15

Y1 - 2021/9/15

N2 - Reaction of [Cp'2ZrMe2] (Cp' = η5-tBuC5H4) with 3,6-di-tert-butylcatechol (H2Cat36) leads to complex [Cp'2ZrCat36] (1). Analogous reaction of [Cp'2ZrMe2] with 3,6-di-tert-butyl-o-benzoquinone (Q36) results in migration of the methyl group from metal to the C6-ring and formation of a complex of 3-tert-butyl-6-methyl-catecholate [Cp'2ZrCat36Me] (2). Both products were characterized with single crystal X-ray diffraction and NMR spectroscopy.

AB - Reaction of [Cp'2ZrMe2] (Cp' = η5-tBuC5H4) with 3,6-di-tert-butylcatechol (H2Cat36) leads to complex [Cp'2ZrCat36] (1). Analogous reaction of [Cp'2ZrMe2] with 3,6-di-tert-butyl-o-benzoquinone (Q36) results in migration of the methyl group from metal to the C6-ring and formation of a complex of 3-tert-butyl-6-methyl-catecholate [Cp'2ZrCat36Me] (2). Both products were characterized with single crystal X-ray diffraction and NMR spectroscopy.

KW - C–C Bond activation

KW - NMR

KW - Quinones

KW - X-ray diffraction analysis

KW - Zirconium

UR - http://www.scopus.com/inward/record.url?scp=85111787581&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2021.121946

DO - 10.1016/j.jorganchem.2021.121946

M3 - Article

AN - SCOPUS:85111787581

VL - 949

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

M1 - 121946

ER -

ID: 29237392