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Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction. / Bobrova, Ludmilla N.; Sadykov, Vladislav A.; Mezentseva, Natalya V. et al.

In: International Journal of Hydrogen Energy, Vol. 41, No. 8, 02.03.2016, p. 4632-4645.

Research output: Contribution to journalArticlepeer-review

Harvard

Bobrova, LN, Sadykov, VA, Mezentseva, NV, Pelipenko, VV, Vernikovskaya, NV, Klenov, OP & Smorygo, OL 2016, 'Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction', International Journal of Hydrogen Energy, vol. 41, no. 8, pp. 4632-4645. https://doi.org/10.1016/j.ijhydene.2016.01.055

APA

Bobrova, L. N., Sadykov, V. A., Mezentseva, N. V., Pelipenko, V. V., Vernikovskaya, N. V., Klenov, O. P., & Smorygo, O. L. (2016). Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction. International Journal of Hydrogen Energy, 41(8), 4632-4645. https://doi.org/10.1016/j.ijhydene.2016.01.055

Vancouver

Bobrova LN, Sadykov VA, Mezentseva NV, Pelipenko VV, Vernikovskaya NV, Klenov OP et al. Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction. International Journal of Hydrogen Energy. 2016 Mar 2;41(8):4632-4645. doi: 10.1016/j.ijhydene.2016.01.055

Author

Bobrova, Ludmilla N. ; Sadykov, Vladislav A. ; Mezentseva, Natalya V. et al. / Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction. In: International Journal of Hydrogen Energy. 2016 ; Vol. 41, No. 8. pp. 4632-4645.

BibTeX

@article{c5d8aaa77ca94e4fb5745686ff4b2b39,
title = "Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction",
abstract = "A conventional Ni + YSZ/YSZ anode half-cell (the Research Center J{\"u}lich) and the Ni + YSZ/YSZ planar half cell washcoated by a layer of the Ru + Ni-doped perovskite-based nanocomposite (Ru + Ni/LaPrMnCr/YSZ) were compared in terms of their activities and selectivities in the steam reforming of methane. The kinetic measurements were carried out in a laboratory scale plate-type reactor, and results were interpreted using computational models. A power-law kinetic model was verified against the experimental data, and parameters were estimated. Both numerical prediction and experimental testing indicate that the nanocomposite coated Ni + YSZ/YSZ plate shows much better catalytic performance under the middle-temperature operating conditions. CFD simulations show that for the high activity of thermally conductive catalytic plates, superior heat transfer performance is observed in the lab-scale reactor. The lab-scale data were successfully up-scaled for the case of steam reforming of natural gas on a structured catalyst at realistic operation conditions. Up to 700°C, the pilot test data obtained with the structured catalyst comprised of three stacked parallel Ni-Al plates (50 × 50 × 1 mm) coated with perovskite-based nanocomposite correlate quite good with the 1-D plug-flow reactor model predictions assuming the proposed kinetics.",
keywords = "CFD simulations, Methane, Ni + YSZ/YSZ anode half-cell, Plate-type reactor, Ru + Ni-doped perovskite-based nanocomposite, Steam reforming",
author = "Bobrova, {Ludmilla N.} and Sadykov, {Vladislav A.} and Mezentseva, {Natalya V.} and Pelipenko, {Vladimir V.} and Vernikovskaya, {Nadezhda V.} and Klenov, {Oleg P.} and Smorygo, {Oleg L.}",
year = "2016",
month = mar,
day = "2",
doi = "10.1016/j.ijhydene.2016.01.055",
language = "English",
volume = "41",
pages = "4632--4645",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier Ltd",
number = "8",

}

RIS

TY - JOUR

T1 - Catalytic performance of structured packages coated with perovskite-based nanocomposite in the methane steam reforming reaction

AU - Bobrova, Ludmilla N.

AU - Sadykov, Vladislav A.

AU - Mezentseva, Natalya V.

AU - Pelipenko, Vladimir V.

AU - Vernikovskaya, Nadezhda V.

AU - Klenov, Oleg P.

AU - Smorygo, Oleg L.

PY - 2016/3/2

Y1 - 2016/3/2

N2 - A conventional Ni + YSZ/YSZ anode half-cell (the Research Center Jülich) and the Ni + YSZ/YSZ planar half cell washcoated by a layer of the Ru + Ni-doped perovskite-based nanocomposite (Ru + Ni/LaPrMnCr/YSZ) were compared in terms of their activities and selectivities in the steam reforming of methane. The kinetic measurements were carried out in a laboratory scale plate-type reactor, and results were interpreted using computational models. A power-law kinetic model was verified against the experimental data, and parameters were estimated. Both numerical prediction and experimental testing indicate that the nanocomposite coated Ni + YSZ/YSZ plate shows much better catalytic performance under the middle-temperature operating conditions. CFD simulations show that for the high activity of thermally conductive catalytic plates, superior heat transfer performance is observed in the lab-scale reactor. The lab-scale data were successfully up-scaled for the case of steam reforming of natural gas on a structured catalyst at realistic operation conditions. Up to 700°C, the pilot test data obtained with the structured catalyst comprised of three stacked parallel Ni-Al plates (50 × 50 × 1 mm) coated with perovskite-based nanocomposite correlate quite good with the 1-D plug-flow reactor model predictions assuming the proposed kinetics.

AB - A conventional Ni + YSZ/YSZ anode half-cell (the Research Center Jülich) and the Ni + YSZ/YSZ planar half cell washcoated by a layer of the Ru + Ni-doped perovskite-based nanocomposite (Ru + Ni/LaPrMnCr/YSZ) were compared in terms of their activities and selectivities in the steam reforming of methane. The kinetic measurements were carried out in a laboratory scale plate-type reactor, and results were interpreted using computational models. A power-law kinetic model was verified against the experimental data, and parameters were estimated. Both numerical prediction and experimental testing indicate that the nanocomposite coated Ni + YSZ/YSZ plate shows much better catalytic performance under the middle-temperature operating conditions. CFD simulations show that for the high activity of thermally conductive catalytic plates, superior heat transfer performance is observed in the lab-scale reactor. The lab-scale data were successfully up-scaled for the case of steam reforming of natural gas on a structured catalyst at realistic operation conditions. Up to 700°C, the pilot test data obtained with the structured catalyst comprised of three stacked parallel Ni-Al plates (50 × 50 × 1 mm) coated with perovskite-based nanocomposite correlate quite good with the 1-D plug-flow reactor model predictions assuming the proposed kinetics.

KW - CFD simulations

KW - Methane

KW - Ni + YSZ/YSZ anode half-cell

KW - Plate-type reactor

KW - Ru + Ni-doped perovskite-based nanocomposite

KW - Steam reforming

UR - http://www.scopus.com/inward/record.url?scp=85027947643&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2016.01.055

DO - 10.1016/j.ijhydene.2016.01.055

M3 - Article

AN - SCOPUS:85027947643

VL - 41

SP - 4632

EP - 4645

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 8

ER -

ID: 25389850