Research output: Contribution to journal › Article › peer-review
Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium. / Zonov, Ya V.; Karpov, V. M.; Mezhenkova, T. V.
In: Russian Journal of Organic Chemistry, Vol. 55, No. 8, 01.08.2019, p. 1103-1111.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium
AU - Zonov, Ya V.
AU - Karpov, V. M.
AU - Mezhenkova, T. V.
N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd.
PY - 2019/8/1
Y1 - 2019/8/1
N2 - The carbonylation of perfluoro-2-R-benzocyclobutenones (R = F, CF3, C2F5, C6F5) in a CO-SbF5 system is accompanied by transformations of the four-membered cycle in the substrate to form polyfluorinated 1H-isochromene derivatives. The reaction of perfluoro-2-R-benzocyclobutenes (R = F, CF3, C2F5) with (CF3CO)2O or CF3COOH in a SbF5 medium in a sealed ampule involves formation of polyfluorobenzocyclobutenones and their carbonylation under the reaction conditions.
AB - The carbonylation of perfluoro-2-R-benzocyclobutenones (R = F, CF3, C2F5, C6F5) in a CO-SbF5 system is accompanied by transformations of the four-membered cycle in the substrate to form polyfluorinated 1H-isochromene derivatives. The reaction of perfluoro-2-R-benzocyclobutenes (R = F, CF3, C2F5) with (CF3CO)2O or CF3COOH in a SbF5 medium in a sealed ampule involves formation of polyfluorobenzocyclobutenones and their carbonylation under the reaction conditions.
KW - antimony pentafluoride
KW - carbonylation
KW - isochromenone
KW - polyfluorinated benzocyclobutenones
UR - http://www.scopus.com/inward/record.url?scp=85073061517&partnerID=8YFLogxK
U2 - 10.1134/S1070428019080086
DO - 10.1134/S1070428019080086
M3 - Article
AN - SCOPUS:85073061517
VL - 55
SP - 1103
EP - 1111
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 8
ER -
ID: 21860338