Capillary zone electrophoresis as a simple approach for the study of p-arsanilic acid transformation in the process of photolytic degradation

Standard

Capillary zone electrophoresis as a simple approach for the study of p-arsanilic acid transformation in the process of photolytic degradation. / Polyakova, Evgeniya V.; Shuvaeva, Olga V.; Koshcheeva, Olga S. et al.

In: Electrophoresis, Vol. 42, No. 6, 03.2021, p. 719-724.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{054dff78faec43258f0c621f7f26ebeb,

title = "Capillary zone electrophoresis as a simple approach for the study of p-arsanilic acid transformation in the process of photolytic degradation",

abstract = "Arsenic aromatic compounds including p-arsanylic acid (pASA) are still widely used in a number of countries as the feed additives in animal breeding resulting in its entering the environment. Under the influence of oxidizing agents or UV radiation, pASA undergoes transformations leading to generation of inorganic arsenic species that are more mobile and toxic than organic ones. On the one hand, an approach based on the treatment of contaminated waters by UV irradiation seems perspective for their detoxification, but the feasibility of this approach depends on the composition of the products forming as a result of photodegradation. In the present work, a CZE was applied for the study of the pASA degradation process during stationary (308 nm) photolysis in the presence of Fe(III)-oxalate complex. A developed assay allowed controlling the parent compounds and also As-containing products of pASA degradation, presented mainly by arsenate and arsenite ions. It was found that the main inorganic derivatives of the pASA photolytic conversions are presented by arsenate and arsenite ions whose ratio depends on the initial amount of pASA and reaction conditions.",

keywords = "Analysis, CZE, Photolysis, ARSENIC COMPOUNDS, AMINO-ACIDS, KINETICS, SPECIATION, INORGANIC ANIONS, PHOTODEGRADATION, ORGANIC-ACIDS, PHOTOOXIDATION, RICE",

author = "Polyakova, {Evgeniya V.} and Shuvaeva, {Olga V.} and Koshcheeva, {Olga S.} and Tyutereva, {Yuliya E.} and Pozdnyakov, {Ivan P.}",

year = "2021",

month = mar,

doi = "10.1002/elps.202000262",

language = "English",

volume = "42",

pages = "719--724",

journal = "Electrophoresis",

issn = "0173-0835",

publisher = "Wiley-VCH Verlag",

number = "6",

}

RIS

TY - JOUR

T1 - Capillary zone electrophoresis as a simple approach for the study of p-arsanilic acid transformation in the process of photolytic degradation

AU - Polyakova, Evgeniya V.

AU - Shuvaeva, Olga V.

AU - Koshcheeva, Olga S.

AU - Tyutereva, Yuliya E.

AU - Pozdnyakov, Ivan P.

PY - 2021/3

Y1 - 2021/3

N2 - Arsenic aromatic compounds including p-arsanylic acid (pASA) are still widely used in a number of countries as the feed additives in animal breeding resulting in its entering the environment. Under the influence of oxidizing agents or UV radiation, pASA undergoes transformations leading to generation of inorganic arsenic species that are more mobile and toxic than organic ones. On the one hand, an approach based on the treatment of contaminated waters by UV irradiation seems perspective for their detoxification, but the feasibility of this approach depends on the composition of the products forming as a result of photodegradation. In the present work, a CZE was applied for the study of the pASA degradation process during stationary (308 nm) photolysis in the presence of Fe(III)-oxalate complex. A developed assay allowed controlling the parent compounds and also As-containing products of pASA degradation, presented mainly by arsenate and arsenite ions. It was found that the main inorganic derivatives of the pASA photolytic conversions are presented by arsenate and arsenite ions whose ratio depends on the initial amount of pASA and reaction conditions.

AB - Arsenic aromatic compounds including p-arsanylic acid (pASA) are still widely used in a number of countries as the feed additives in animal breeding resulting in its entering the environment. Under the influence of oxidizing agents or UV radiation, pASA undergoes transformations leading to generation of inorganic arsenic species that are more mobile and toxic than organic ones. On the one hand, an approach based on the treatment of contaminated waters by UV irradiation seems perspective for their detoxification, but the feasibility of this approach depends on the composition of the products forming as a result of photodegradation. In the present work, a CZE was applied for the study of the pASA degradation process during stationary (308 nm) photolysis in the presence of Fe(III)-oxalate complex. A developed assay allowed controlling the parent compounds and also As-containing products of pASA degradation, presented mainly by arsenate and arsenite ions. It was found that the main inorganic derivatives of the pASA photolytic conversions are presented by arsenate and arsenite ions whose ratio depends on the initial amount of pASA and reaction conditions.

KW - Analysis

KW - CZE

KW - Photolysis

KW - ARSENIC COMPOUNDS

KW - AMINO-ACIDS

KW - KINETICS

KW - SPECIATION

KW - INORGANIC ANIONS

KW - PHOTODEGRADATION

KW - ORGANIC-ACIDS

KW - PHOTOOXIDATION

KW - RICE

UR - http://www.scopus.com/inward/record.url?scp=85096869913&partnerID=8YFLogxK

U2 - 10.1002/elps.202000262

DO - 10.1002/elps.202000262

M3 - Article

C2 - 33185273

AN - SCOPUS:85096869913

VL - 42

SP - 719

EP - 724

JO - Electrophoresis

JF - Electrophoresis

SN - 0173-0835

IS - 6

ER -

ID: 26135201