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Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas. / Yakovleva, E. Yu; Patrushev, Yu V.; Pai, Z. P.

In: Russian Journal of Physical Chemistry A, Vol. 92, No. 5, 01.05.2018, p. 1018-1024.

Research output: Contribution to journal › Article › peer-review

Harvard

Yakovleva, EY, Patrushev, YV & Pai, ZP 2018, 'Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas', Russian Journal of Physical Chemistry A, vol. 92, no. 5, pp. 1018-1024. https://doi.org/10.1134/S0036024418050357

APA

Yakovleva, E. Y., Patrushev, Y. V., & Pai, Z. P. (2018). Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas. Russian Journal of Physical Chemistry A, 92(5), 1018-1024. https://doi.org/10.1134/S0036024418050357

Vancouver

Yakovleva EY, Patrushev YV, Pai ZP. Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas. Russian Journal of Physical Chemistry A. 2018 May 1;92(5):1018-1024. doi: 10.1134/S0036024418050357

Author

Yakovleva, E. Yu ; Patrushev, Yu V. ; Pai, Z. P. / Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas. In: Russian Journal of Physical Chemistry A. 2018 ; Vol. 92, No. 5. pp. 1018-1024.

BibTeX

@article{f02cc33f19f346eb938d1591a5931fc5,
title = "Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas",
abstract = "The chromatographic properties of capillary columns prepared using functionalized poly(1- trimethylsilyl-1-propyne) (PTMSP) are evaluated and compared with the performance of a commercial column with divinylbenzene polymer sorbent. The loading capacity of a PTMSP column with dimensions of 30 m × 0.53 mm × 0.8 μm is shown to be about 2.5 times higher than that of a divinylbenzene polymer column with a diameter of 0.32 mm and a film thickness of 10 μm. The increased value of the background current for PTMSP columns at 220°C is explained by the presence of non-polar bulky substituents in the polymer chain. Differences in the order of elution are found for the following pairs of compounds: acetylene-ethylene; ethane–water; butene-1–isobutane; and sulfur dioxide–carbonyl sulfide. On a column with the functionalized PTMC, analysis of a mixture composition close to natural gas is found to be complete within 27 min.",
keywords = "functionalized poly(1-trimethylsilyl-1-propyne), hydrocarbons, inorganic sulfur-containing gases, mercaptans, POLYMER, CHROMATOGRAPHIC PROPERTIES, SEPARATION",
author = "Yakovleva, {E. Yu} and Patrushev, {Yu V.} and Pai, {Z. P.}",
year = "2018",
month = may,
day = "1",
doi = "10.1134/S0036024418050357",
language = "English",
volume = "92",
pages = "1018--1024",
journal = "Russian Journal of Physical Chemistry A",
issn = "0036-0244",
publisher = "PLEIADES PUBLISHING INC",
number = "5",

}

RIS

TY - JOUR

T1 - Capillary Columns with a Sorbent Based on Functionalized Poly(1-Trimethylsilyl-1-Propyne) for the Elution Analysis of Natural Gas

AU - Yakovleva, E. Yu

AU - Patrushev, Yu V.

AU - Pai, Z. P.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - The chromatographic properties of capillary columns prepared using functionalized poly(1- trimethylsilyl-1-propyne) (PTMSP) are evaluated and compared with the performance of a commercial column with divinylbenzene polymer sorbent. The loading capacity of a PTMSP column with dimensions of 30 m × 0.53 mm × 0.8 μm is shown to be about 2.5 times higher than that of a divinylbenzene polymer column with a diameter of 0.32 mm and a film thickness of 10 μm. The increased value of the background current for PTMSP columns at 220°C is explained by the presence of non-polar bulky substituents in the polymer chain. Differences in the order of elution are found for the following pairs of compounds: acetylene-ethylene; ethane–water; butene-1–isobutane; and sulfur dioxide–carbonyl sulfide. On a column with the functionalized PTMC, analysis of a mixture composition close to natural gas is found to be complete within 27 min.

AB - The chromatographic properties of capillary columns prepared using functionalized poly(1- trimethylsilyl-1-propyne) (PTMSP) are evaluated and compared with the performance of a commercial column with divinylbenzene polymer sorbent. The loading capacity of a PTMSP column with dimensions of 30 m × 0.53 mm × 0.8 μm is shown to be about 2.5 times higher than that of a divinylbenzene polymer column with a diameter of 0.32 mm and a film thickness of 10 μm. The increased value of the background current for PTMSP columns at 220°C is explained by the presence of non-polar bulky substituents in the polymer chain. Differences in the order of elution are found for the following pairs of compounds: acetylene-ethylene; ethane–water; butene-1–isobutane; and sulfur dioxide–carbonyl sulfide. On a column with the functionalized PTMC, analysis of a mixture composition close to natural gas is found to be complete within 27 min.

KW - functionalized poly(1-trimethylsilyl-1-propyne)

KW - hydrocarbons

KW - inorganic sulfur-containing gases

KW - mercaptans

KW - POLYMER

KW - CHROMATOGRAPHIC PROPERTIES

KW - SEPARATION

UR - http://www.scopus.com/inward/record.url?scp=85045761556&partnerID=8YFLogxK

U2 - 10.1134/S0036024418050357

DO - 10.1134/S0036024418050357

M3 - Article

AN - SCOPUS:85045761556

VL - 92

SP - 1018

EP - 1024

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 5

ER -

ID: 12799669