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Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. / Usol’tsev, A. N.; Petrov, M. D.; Korol’kov, I. V. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 47, No. 9, 09.2021, p. 620-625.

Research output: Contribution to journal › Article › peer-review

Harvard

Usol’tsev, AN, Petrov, MD, Korol’kov, IV, Sokolov, MN, Blatov, VA & Adonin, SA 2021, 'Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 47, no. 9, pp. 620-625. https://doi.org/10.1134/S107032842108008X

APA

Usol’tsev, A. N., Petrov, M. D., Korol’kov, I. V., Sokolov, M. N., Blatov, V. A., & Adonin, S. A. (2021). Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 47(9), 620-625. https://doi.org/10.1134/S107032842108008X

Vancouver

Usol’tsev AN, Petrov MD, Korol’kov IV, Sokolov MN, Blatov VA, Adonin SA. Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 Sept;47(9):620-625. doi: 10.1134/S107032842108008X

Author

Usol’tsev, A. N. ; Petrov, M. D. ; Korol’kov, I. V. et al. / Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2021 ; Vol. 47, No. 9. pp. 620-625.

BibTeX

@article{a2bfade917634f75b3ea4fb0dce0d169,
title = "Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity",
abstract = "The reaction of solutions of Sb2O3 and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC4)Br2) in concentrated HBr affords polymorphs: binuclear (4-MePyC2)[Sb2Br8] (I) or tetranuclear (4-MePyC4)2[Sb4Br16] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).",
keywords = "antimony, bromide complexes, polymorphism, polynuclear complexes, X-ray structure analysis",
author = "Usol{\textquoteright}tsev, {A. N.} and Petrov, {M. D.} and Korol{\textquoteright}kov, {I. V.} and Sokolov, {M. N.} and Blatov, {V. A.} and Adonin, {S. A.}",
note = "Funding Information: This work was supported by the Russian Science Foundation, project no. 18-73-10040. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = sep,
doi = "10.1134/S107032842108008X",
language = "English",
volume = "47",
pages = "620--625",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "9",

}

RIS

TY - JOUR

T1 - Bromide Complexes of Sb(III) with the 4,4'-Dimethyl-1,1'-Butanediylbis(pyridinium) Cation: Unexpected Formation of Polymorphs with Complex Cations of Various Nuclearity

AU - Usol’tsev, A. N.

AU - Petrov, M. D.

AU - Korol’kov, I. V.

AU - Sokolov, M. N.

AU - Blatov, V. A.

AU - Adonin, S. A.

N1 - Funding Information: This work was supported by the Russian Science Foundation, project no. 18-73-10040. Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/9

Y1 - 2021/9

N2 - The reaction of solutions of Sb2O3 and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC4)Br2) in concentrated HBr affords polymorphs: binuclear (4-MePyC2)[Sb2Br8] (I) or tetranuclear (4-MePyC4)2[Sb4Br16] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).

AB - The reaction of solutions of Sb2O3 and 4,4'-dimethyl-1,1'-butanediylbis(pyridinium) dibromide ((4-MePyC4)Br2) in concentrated HBr affords polymorphs: binuclear (4-MePyC2)[Sb2Br8] (I) or tetranuclear (4-MePyC4)2[Sb4Br16] (II) complexes, depending on the reaction conditions. The structures of the complexes are studied by X-ray structure analysis (CIF files CCDC nos. 2061368 (I) and 2061369 (II)).

KW - antimony

KW - bromide complexes

KW - polymorphism

KW - polynuclear complexes

KW - X-ray structure analysis

UR - http://www.scopus.com/inward/record.url?scp=85114729813&partnerID=8YFLogxK

U2 - 10.1134/S107032842108008X

DO - 10.1134/S107032842108008X

M3 - Article

AN - SCOPUS:85114729813

VL - 47

SP - 620

EP - 625

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 9

ER -

ID: 34189862