Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family

Standard

Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family. / Gorokh, Igor D.; Adonin, Sergey A.; Usoltsev, Andrey N. et al.

In: Journal of Molecular Structure, Vol. 1199, 126955, 05.01.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Gorokh, ID, Adonin, SA, Usoltsev, AN, Novikov, AS, Samsonenko, DG, Zakharov, SV, Sokolov, MN & Fedin, VP 2020, 'Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family', Journal of Molecular Structure, vol. 1199, 126955. https://doi.org/10.1016/j.molstruc.2019.126955

APA

Gorokh, I. D., Adonin, S. A., Usoltsev, A. N., Novikov, A. S., Samsonenko, D. G., Zakharov, S. V., Sokolov, M. N., & Fedin, V. P. (2020). Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family. Journal of Molecular Structure, 1199, [126955]. https://doi.org/10.1016/j.molstruc.2019.126955

Vancouver

Gorokh ID, Adonin SA, Usoltsev AN, Novikov AS, Samsonenko DG, Zakharov SV et al. Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family. Journal of Molecular Structure. 2020 Jan 5;1199:126955. doi: 10.1016/j.molstruc.2019.126955

Author

Gorokh, Igor D. ; Adonin, Sergey A. ; Usoltsev, Andrey N. et al. / Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family. In: Journal of Molecular Structure. 2020 ; Vol. 1199.

BibTeX

@article{40baa8869f6944468d886ea48af80ab0,

title = "Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family",

abstract = "Two bromobismuthate (III) complexes containing 4-bromobenzyl-substituted pyridinium cations – (1-(4-BrBz)Py)3[Bi2Br9] (1) and (1-(4-BrBz)-2-MePy)3[BiBr6] (2) – were prepared by reactions of Bi2O3 and corresponding pyridinium bromides in HBr. In the structure of 1 there are weak contacts between the Br atoms of 1-(4-BrBz)Py+ and bromide ligands of [Bi2Br9]3-, while in the case of 2 such interactions are absent. The contributions of halogen and hydrogen bonding were estimated by Hirshfeld surface analysis (HSA); additionally, energies of Br⋯Br type I halogen-halogen contacts were calculated.",

keywords = "Bismuth, Halide complexes, Hirshfeld surface analysis, Supramolecular contacts, HIRSHFELD SURFACE-ANALYSIS, CRYSTAL-STRUCTURES, NONCOVALENT INTERACTIONS, VIBRATIONAL-SPECTRA, BR, TRANSITION, HYBRID MATERIAL, CHLOROBISMUTHATE(III), MAGNETIC-PROPERTIES, HALOGEN BOND",

author = "Gorokh, {Igor D.} and Adonin, {Sergey A.} and Usoltsev, {Andrey N.} and Novikov, {Alexander S.} and Samsonenko, {Denis G.} and Zakharov, {Sergey V.} and Sokolov, {Maxim N.} and Fedin, {Vladimir P.}",

year = "2020",

month = jan,

day = "5",

doi = "10.1016/j.molstruc.2019.126955",

language = "English",

volume = "1199",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Bromide complexes of bismuth with 4-bromobenzyl-substituted cations of pyridinium family

AU - Gorokh, Igor D.

AU - Adonin, Sergey A.

AU - Usoltsev, Andrey N.

AU - Novikov, Alexander S.

AU - Samsonenko, Denis G.

AU - Zakharov, Sergey V.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

PY - 2020/1/5

Y1 - 2020/1/5

N2 - Two bromobismuthate (III) complexes containing 4-bromobenzyl-substituted pyridinium cations – (1-(4-BrBz)Py)3[Bi2Br9] (1) and (1-(4-BrBz)-2-MePy)3[BiBr6] (2) – were prepared by reactions of Bi2O3 and corresponding pyridinium bromides in HBr. In the structure of 1 there are weak contacts between the Br atoms of 1-(4-BrBz)Py+ and bromide ligands of [Bi2Br9]3-, while in the case of 2 such interactions are absent. The contributions of halogen and hydrogen bonding were estimated by Hirshfeld surface analysis (HSA); additionally, energies of Br⋯Br type I halogen-halogen contacts were calculated.

AB - Two bromobismuthate (III) complexes containing 4-bromobenzyl-substituted pyridinium cations – (1-(4-BrBz)Py)3[Bi2Br9] (1) and (1-(4-BrBz)-2-MePy)3[BiBr6] (2) – were prepared by reactions of Bi2O3 and corresponding pyridinium bromides in HBr. In the structure of 1 there are weak contacts between the Br atoms of 1-(4-BrBz)Py+ and bromide ligands of [Bi2Br9]3-, while in the case of 2 such interactions are absent. The contributions of halogen and hydrogen bonding were estimated by Hirshfeld surface analysis (HSA); additionally, energies of Br⋯Br type I halogen-halogen contacts were calculated.

KW - Bismuth

KW - Halide complexes

KW - Hirshfeld surface analysis

KW - Supramolecular contacts

KW - HIRSHFELD SURFACE-ANALYSIS

KW - CRYSTAL-STRUCTURES

KW - NONCOVALENT INTERACTIONS

KW - VIBRATIONAL-SPECTRA

KW - BR

KW - TRANSITION

KW - HYBRID MATERIAL

KW - CHLOROBISMUTHATE(III)

KW - MAGNETIC-PROPERTIES

KW - HALOGEN BOND

UR - http://www.scopus.com/inward/record.url?scp=85071005408&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2019.126955

DO - 10.1016/j.molstruc.2019.126955

M3 - Article

AN - SCOPUS:85071005408

VL - 1199

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

M1 - 126955

ER -

ID: 21343697