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Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt. / Зайцева, Татьяна Витальевна; Задесенец, Андрей Владимирович; Филатов, Евгений Юрьевич et al.

In: Journal of Structural Chemistry, Vol. 65, No. 2, 02.2024, p. 301-312.

Research output: Contribution to journal › Article › peer-review

Harvard

Зайцева, ТВ, Задесенец, АВ, Филатов, ЕЮ, Сухих, АС & Коренев, СВ 2024, 'Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt', Journal of Structural Chemistry, vol. 65, no. 2, pp. 301-312. https://doi.org/10.1134/s0022476624020082

APA

Зайцева, Т. В., Задесенец, А. В., Филатов, Е. Ю., Сухих, А. С., & Коренев, С. В. (2024). Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt. Journal of Structural Chemistry, 65(2), 301-312. https://doi.org/10.1134/s0022476624020082

Vancouver

Зайцева ТВ, Задесенец АВ, Филатов ЕЮ, Сухих АС, Коренев СВ. Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt. Journal of Structural Chemistry. 2024 Feb;65(2):301-312. doi: 10.1134/s0022476624020082

Author

Зайцева, Татьяна Витальевна ; Задесенец, Андрей Владимирович ; Филатов, Евгений Юрьевич et al. / Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt. In: Journal of Structural Chemistry. 2024 ; Vol. 65, No. 2. pp. 301-312.

BibTeX

@article{d1a0ee6e3ba1472aa0c2746c8c9e2eee,
title = "Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt",
abstract = "New coordination compounds, sodium trans-bis(oxalato)diaqua-iridate(III) dihydrate Na[Ir(H2O)2(C2 O4)2]·2H2O and trans-bis(oxalato)diaquairidic acid H5O2[Ir(H2O)2(C2O4)2], are prepared. The substances are characterized by single-crystal XRD, powder XRD, and IR spectroscopy. Crystal data for Na[Ir(H2O)2(C2O4)2]·2H2O: space group, a = 5.2456(7) {\AA}, b = 6.4999(8) {\AA}, c = 8.237(1) {\AA}, α = 98.162(6)°, β = 92.005(6)°, γ = 112.043(4)°, Z = 1; for H5O2[Ir(H2O)2(C2O4)2]: space group, a = 4.6903(2) {\AA}, b = 6.0053(3) {\AA}, c = 9.1527(5) {\AA}, α = 75.843(2)°, β = 84.270(2)°, γ = 82.413(2)°, Z = 1. The coordination sphere of iridium is a distorted octahedron. The Na[Ir(H2O)2(C2O4)2]·2H2O structure is similar to those of MC2O4·2H2O divalent metal oxalates (M = Mn, Fe, Co, Ni, Cu, Zn). The Zundel cation in the trans-bis(oxalato)iridic acid is located discretely.",
keywords = "рентгеноструктурный анализ, иридий, щавелевая кислота, оксалатокомплексы, катион Цунделя, XRD, Zundel cation, iridium, oxalate complexes, oxalic acid",
author = "Зайцева, {Татьяна Витальевна} and Задесенец, {Андрей Владимирович} and Филатов, {Евгений Юрьевич} and Сухих, {Александр Сергеевич} and Коренев, {Сергей Васильевич}",
note = "This work was funded by the Russian Science Foundation (project No. 21-73-20203).",
year = "2024",
month = feb,
doi = "10.1134/s0022476624020082",
language = "English",
volume = "65",
pages = "301--312",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Bisoxalateiridium Acid, a New Rare Example of a Crystal Complex Acid with the H5O2+ Cation, and Its Sodium Salt

AU - Зайцева, Татьяна Витальевна

AU - Задесенец, Андрей Владимирович

AU - Филатов, Евгений Юрьевич

AU - Сухих, Александр Сергеевич

AU - Коренев, Сергей Васильевич

N1 - This work was funded by the Russian Science Foundation (project No. 21-73-20203).

PY - 2024/2

Y1 - 2024/2

N2 - New coordination compounds, sodium trans-bis(oxalato)diaqua-iridate(III) dihydrate Na[Ir(H2O)2(C2 O4)2]·2H2O and trans-bis(oxalato)diaquairidic acid H5O2[Ir(H2O)2(C2O4)2], are prepared. The substances are characterized by single-crystal XRD, powder XRD, and IR spectroscopy. Crystal data for Na[Ir(H2O)2(C2O4)2]·2H2O: space group, a = 5.2456(7) Å, b = 6.4999(8) Å, c = 8.237(1) Å, α = 98.162(6)°, β = 92.005(6)°, γ = 112.043(4)°, Z = 1; for H5O2[Ir(H2O)2(C2O4)2]: space group, a = 4.6903(2) Å, b = 6.0053(3) Å, c = 9.1527(5) Å, α = 75.843(2)°, β = 84.270(2)°, γ = 82.413(2)°, Z = 1. The coordination sphere of iridium is a distorted octahedron. The Na[Ir(H2O)2(C2O4)2]·2H2O structure is similar to those of MC2O4·2H2O divalent metal oxalates (M = Mn, Fe, Co, Ni, Cu, Zn). The Zundel cation in the trans-bis(oxalato)iridic acid is located discretely.

AB - New coordination compounds, sodium trans-bis(oxalato)diaqua-iridate(III) dihydrate Na[Ir(H2O)2(C2 O4)2]·2H2O and trans-bis(oxalato)diaquairidic acid H5O2[Ir(H2O)2(C2O4)2], are prepared. The substances are characterized by single-crystal XRD, powder XRD, and IR spectroscopy. Crystal data for Na[Ir(H2O)2(C2O4)2]·2H2O: space group, a = 5.2456(7) Å, b = 6.4999(8) Å, c = 8.237(1) Å, α = 98.162(6)°, β = 92.005(6)°, γ = 112.043(4)°, Z = 1; for H5O2[Ir(H2O)2(C2O4)2]: space group, a = 4.6903(2) Å, b = 6.0053(3) Å, c = 9.1527(5) Å, α = 75.843(2)°, β = 84.270(2)°, γ = 82.413(2)°, Z = 1. The coordination sphere of iridium is a distorted octahedron. The Na[Ir(H2O)2(C2O4)2]·2H2O structure is similar to those of MC2O4·2H2O divalent metal oxalates (M = Mn, Fe, Co, Ni, Cu, Zn). The Zundel cation in the trans-bis(oxalato)iridic acid is located discretely.

KW - рентгеноструктурный анализ

KW - иридий

KW - щавелевая кислота

KW - оксалатокомплексы

KW - катион Цунделя

KW - XRD

KW - Zundel cation

KW - iridium

KW - oxalate complexes

KW - oxalic acid

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85186544729&origin=inward&txGid=62055cd31c7f19b9101f9851515464b4

UR - https://www.mendeley.com/catalogue/e02c01bf-8dc4-3552-8a40-386d9323464d/

U2 - 10.1134/s0022476624020082

DO - 10.1134/s0022476624020082

M3 - Article

VL - 65

SP - 301

EP - 312

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 60498453