Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate

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Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate. / Ghazaryan, V. V.; Drebushchak, T. N.; Boldyreva, E. V. et al.

In: Structural Chemistry, Vol. 31, No. 5, 01.10.2020, p. 1919-1925.

Research output: Contribution to journal › Article › peer-review

Harvard

Ghazaryan, VV, Drebushchak, TN , Boldyreva, EV & Petrosyan, AM 2020, 'Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate', Structural Chemistry, vol. 31, no. 5, pp. 1919-1925. https://doi.org/10.1007/s11224-020-01610-z

APA

Ghazaryan, V. V., Drebushchak, T. N., Boldyreva, E. V., & Petrosyan, A. M. (2020). Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate. Structural Chemistry, 31(5), 1919-1925. https://doi.org/10.1007/s11224-020-01610-z

Vancouver

Ghazaryan VV, Drebushchak TN , Boldyreva EV, Petrosyan AM. Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate. Structural Chemistry. 2020 Oct 1;31(5):1919-1925. doi: 10.1007/s11224-020-01610-z

Author

Ghazaryan, V. V. ; Drebushchak, T. N. ; Boldyreva, E. V. et al. / Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate. In: Structural Chemistry. 2020 ; Vol. 31, No. 5. pp. 1919-1925.

BibTeX

@article{63356ea6266247d1908364872485c9f8,

title = "Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate",

abstract = "Two new crystalline compounds of l-cysteine have been obtained: bis-l-cysteinium sulfate (l-CysH)2SO4 (I) and l-cysteinium methanesulfonate (l-CysH)CH3SO3 (II). Both crystal structures belong to the orthorhombic space group P212121. They consist of one formula unit in the asymmetric unit. Structures are stabilized due to hydrogen bonds, which are mainly of type O–H···O and N–H···O. The shortest are hydrogen bonds O–H···O between l-cysteinium cations and sulfate anion with the O···O distances of 2.567(4) {\AA} and 2.534(4) {\AA} in (I) and l-cysteinium cation and methanesulfonate anion with the O···O distance of 2.577(3) {\AA} in (II). Infrared spectra were registered and discussed.",

keywords = "Crystal structure, l-Cysteine, Methanesulfonate, Sulfate, Vibrational spectra, CRYSTAL-STRUCTURE, GROWTH, MONOHYDRATE, FAMILY",

author = "Ghazaryan, {V. V.} and Drebushchak, {T. N.} and Boldyreva, {E. V.} and Petrosyan, {A. M.}",

year = "2020",

month = oct,

day = "1",

doi = "10.1007/s11224-020-01610-z",

language = "English",

volume = "31",

pages = "1919--1925",

journal = "Structural Chemistry",

issn = "1040-0400",

publisher = "Springer New York",

number = "5",

}

RIS

TY - JOUR

T1 - Bis-l-Cysteinium sulfate and l-cysteinium methanesulfonate

AU - Ghazaryan, V. V.

AU - Drebushchak, T. N.

AU - Boldyreva, E. V.

AU - Petrosyan, A. M.

PY - 2020/10/1

Y1 - 2020/10/1

N2 - Two new crystalline compounds of l-cysteine have been obtained: bis-l-cysteinium sulfate (l-CysH)2SO4 (I) and l-cysteinium methanesulfonate (l-CysH)CH3SO3 (II). Both crystal structures belong to the orthorhombic space group P212121. They consist of one formula unit in the asymmetric unit. Structures are stabilized due to hydrogen bonds, which are mainly of type O–H···O and N–H···O. The shortest are hydrogen bonds O–H···O between l-cysteinium cations and sulfate anion with the O···O distances of 2.567(4) Å and 2.534(4) Å in (I) and l-cysteinium cation and methanesulfonate anion with the O···O distance of 2.577(3) Å in (II). Infrared spectra were registered and discussed.

AB - Two new crystalline compounds of l-cysteine have been obtained: bis-l-cysteinium sulfate (l-CysH)2SO4 (I) and l-cysteinium methanesulfonate (l-CysH)CH3SO3 (II). Both crystal structures belong to the orthorhombic space group P212121. They consist of one formula unit in the asymmetric unit. Structures are stabilized due to hydrogen bonds, which are mainly of type O–H···O and N–H···O. The shortest are hydrogen bonds O–H···O between l-cysteinium cations and sulfate anion with the O···O distances of 2.567(4) Å and 2.534(4) Å in (I) and l-cysteinium cation and methanesulfonate anion with the O···O distance of 2.577(3) Å in (II). Infrared spectra were registered and discussed.

KW - Crystal structure

KW - l-Cysteine

KW - Methanesulfonate

KW - Sulfate

KW - Vibrational spectra

KW - CRYSTAL-STRUCTURE

KW - GROWTH

KW - MONOHYDRATE

KW - FAMILY

UR - http://www.scopus.com/inward/record.url?scp=85089390368&partnerID=8YFLogxK

U2 - 10.1007/s11224-020-01610-z

DO - 10.1007/s11224-020-01610-z

M3 - Article

AN - SCOPUS:85089390368

VL - 31

SP - 1919

EP - 1925

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

IS - 5

ER -

ID: 24963537