Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
Asymmetric C—H Oxygenation Reactions. / Брыляков, Константин Петрович.
Handbook of CH-Functionalization. Chapter 7: Biocatalysis and Asymmetric Catalysis. ed. / Debabrata Maiti. JOHN WILEY & SONS LTD, 2022. 7 (Handbook of CH‐Functionalization).Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review
}
TY - CHAP
T1 - Asymmetric C—H Oxygenation Reactions
AU - Брыляков, Константин Петрович
N1 - Konstantin P. Bryliakov Asymmetric C-H Oxygenation Reactions // Handbook of CH-Functionalization. Chapter 7: Biocatalysis and Asymmetric Catalysis
PY - 2022
Y1 - 2022
N2 - This article surveys the catalytic approaches to asymmetric oxygenation of aliphatic C-H groups of organic molecules. The progress of catalysts, both transition metal-based and organocatalysts (excluding enzymatic systems), over the last three decades is analyzed, with a focus on synthetic aspects of the title oxidative transformations. Herewith, stereoselective processes relying on enantioselective oxofunctionalizations (essentially, net hydroxylations) of prochiral C-H groups, as well as oxidative desymmetrizations (through either ketonization or hydroxylation) are considered.This account mostly puts forward environmentally benign processes and catalysts, including biomimetic, or bioinspired, catalyst systems. Basic elements of the state-of-the-art mechanistic landscape of stereoselective C-H oxygenations are discussed briefly.
AB - This article surveys the catalytic approaches to asymmetric oxygenation of aliphatic C-H groups of organic molecules. The progress of catalysts, both transition metal-based and organocatalysts (excluding enzymatic systems), over the last three decades is analyzed, with a focus on synthetic aspects of the title oxidative transformations. Herewith, stereoselective processes relying on enantioselective oxofunctionalizations (essentially, net hydroxylations) of prochiral C-H groups, as well as oxidative desymmetrizations (through either ketonization or hydroxylation) are considered.This account mostly puts forward environmentally benign processes and catalysts, including biomimetic, or bioinspired, catalyst systems. Basic elements of the state-of-the-art mechanistic landscape of stereoselective C-H oxygenations are discussed briefly.
UR - https://www.mendeley.com/catalogue/639094ab-1c1a-3a7b-8d3f-8019b4c95727/
U2 - 10.1002/9783527834242.chf0133
DO - 10.1002/9783527834242.chf0133
M3 - Chapter
SN - 9783527834242
T3 - Handbook of CH‐Functionalization
BT - Handbook of CH-Functionalization. Chapter 7: Biocatalysis and Asymmetric Catalysis
A2 - Maiti, Debabrata
PB - JOHN WILEY & SONS LTD
ER -
ID: 42177641