Standard

Analysis of methane hydrate nucleation in water-in-oil emulsions : Isothermal vs constant cooling ramp method and new method for data treatment. / Shestakov, V. A.; Sagidullin, A. K.; Stoporev, A. S. et al.

In: Journal of Molecular Liquids, Vol. 318, 114018, 15.11.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Shestakov, VA, Sagidullin, AK, Stoporev, AS, Grachev, EV & Manakov, AY 2020, 'Analysis of methane hydrate nucleation in water-in-oil emulsions: Isothermal vs constant cooling ramp method and new method for data treatment', Journal of Molecular Liquids, vol. 318, 114018. https://doi.org/10.1016/j.molliq.2020.114018

APA

Shestakov, V. A., Sagidullin, A. K., Stoporev, A. S., Grachev, E. V., & Manakov, A. Y. (2020). Analysis of methane hydrate nucleation in water-in-oil emulsions: Isothermal vs constant cooling ramp method and new method for data treatment. Journal of Molecular Liquids, 318, [114018]. https://doi.org/10.1016/j.molliq.2020.114018

Vancouver

Shestakov VA, Sagidullin AK, Stoporev AS, Grachev EV, Manakov AY. Analysis of methane hydrate nucleation in water-in-oil emulsions: Isothermal vs constant cooling ramp method and new method for data treatment. Journal of Molecular Liquids. 2020 Nov 15;318:114018. doi: 10.1016/j.molliq.2020.114018

Author

Shestakov, V. A. ; Sagidullin, A. K. ; Stoporev, A. S. et al. / Analysis of methane hydrate nucleation in water-in-oil emulsions : Isothermal vs constant cooling ramp method and new method for data treatment. In: Journal of Molecular Liquids. 2020 ; Vol. 318.

BibTeX

@article{8600aa8c435c47debdacfba8b91ac621,
title = "Analysis of methane hydrate nucleation in water-in-oil emulsions: Isothermal vs constant cooling ramp method and new method for data treatment",
abstract = "Temperature dependence of methane hydrate nucleation rate in 50 wt% water in oil emulsion was studied within the temperature range from +2 to −6 °C (supercooling values: 13–21 °C). It turned out that the temperature dependence of nucleation rate in this temperature interval cannot be described by the equations of the classical nucleation theory. This point is discussed with use of available literature data. An approach to the analysis of isothermal survival curves is suggested. Using the approach allows us to establish the amount of nucleation centers in the system and their relative activity. A probable number of nucleation centers and the effect of temperature on the manifestation activity of these centers were determined for the obtained experimental data.",
keywords = "Gas hydrate, Methane, Nucleation, Water in oil emulsion, FREEZING NUCLEATION, PARTICLES, CURVES, NANOPARTICLES, PARAMETERIZATION, DSC, KINETICS, FORMATION PROBABILITY-DISTRIBUTIONS, GAS, HETEROGENEOUS ICE NUCLEATION",
author = "Shestakov, {V. A.} and Sagidullin, {A. K.} and Stoporev, {A. S.} and Grachev, {E. V.} and Manakov, {A. Yu}",
year = "2020",
month = nov,
day = "15",
doi = "10.1016/j.molliq.2020.114018",
language = "English",
volume = "318",
journal = "Journal of Molecular Liquids",
issn = "0167-7322",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Analysis of methane hydrate nucleation in water-in-oil emulsions

T2 - Isothermal vs constant cooling ramp method and new method for data treatment

AU - Shestakov, V. A.

AU - Sagidullin, A. K.

AU - Stoporev, A. S.

AU - Grachev, E. V.

AU - Manakov, A. Yu

PY - 2020/11/15

Y1 - 2020/11/15

N2 - Temperature dependence of methane hydrate nucleation rate in 50 wt% water in oil emulsion was studied within the temperature range from +2 to −6 °C (supercooling values: 13–21 °C). It turned out that the temperature dependence of nucleation rate in this temperature interval cannot be described by the equations of the classical nucleation theory. This point is discussed with use of available literature data. An approach to the analysis of isothermal survival curves is suggested. Using the approach allows us to establish the amount of nucleation centers in the system and their relative activity. A probable number of nucleation centers and the effect of temperature on the manifestation activity of these centers were determined for the obtained experimental data.

AB - Temperature dependence of methane hydrate nucleation rate in 50 wt% water in oil emulsion was studied within the temperature range from +2 to −6 °C (supercooling values: 13–21 °C). It turned out that the temperature dependence of nucleation rate in this temperature interval cannot be described by the equations of the classical nucleation theory. This point is discussed with use of available literature data. An approach to the analysis of isothermal survival curves is suggested. Using the approach allows us to establish the amount of nucleation centers in the system and their relative activity. A probable number of nucleation centers and the effect of temperature on the manifestation activity of these centers were determined for the obtained experimental data.

KW - Gas hydrate

KW - Methane

KW - Nucleation

KW - Water in oil emulsion

KW - FREEZING NUCLEATION

KW - PARTICLES

KW - CURVES

KW - NANOPARTICLES

KW - PARAMETERIZATION

KW - DSC

KW - KINETICS

KW - FORMATION PROBABILITY-DISTRIBUTIONS

KW - GAS

KW - HETEROGENEOUS ICE NUCLEATION

UR - http://www.scopus.com/inward/record.url?scp=85089752478&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2020.114018

DO - 10.1016/j.molliq.2020.114018

M3 - Article

AN - SCOPUS:85089752478

VL - 318

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

SN - 0167-7322

M1 - 114018

ER -

ID: 25296506