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An XPS Study of the Interaction of a Palladium Foil with NO 2. / Smirnov, M. Yu; Klembovskii, I. O.; Kalinkin, A. V. et al.

In: Kinetics and Catalysis, Vol. 59, No. 6, 01.11.2018, p. 786-791.

Research output: Contribution to journal › Article › peer-review

Harvard

Smirnov, MY, Klembovskii, IO, Kalinkin, AV & Bukhtiyarov, VI 2018, 'An XPS Study of the Interaction of a Palladium Foil with NO 2', Kinetics and Catalysis, vol. 59, no. 6, pp. 786-791. https://doi.org/10.1134/S0023158418060150

APA

Smirnov, M. Y., Klembovskii, I. O., Kalinkin, A. V., & Bukhtiyarov, V. I. (2018). An XPS Study of the Interaction of a Palladium Foil with NO 2. Kinetics and Catalysis, 59(6), 786-791. https://doi.org/10.1134/S0023158418060150

Vancouver

Smirnov MY, Klembovskii IO, Kalinkin AV, Bukhtiyarov VI. An XPS Study of the Interaction of a Palladium Foil with NO 2. Kinetics and Catalysis. 2018 Nov 1;59(6):786-791. doi: 10.1134/S0023158418060150

Author

Smirnov, M. Yu ; Klembovskii, I. O. ; Kalinkin, A. V. et al. / An XPS Study of the Interaction of a Palladium Foil with NO 2. In: Kinetics and Catalysis. 2018 ; Vol. 59, No. 6. pp. 786-791.

BibTeX

@article{1672d5aeb31b44eba59352b317f3aecd,
title = "An XPS Study of the Interaction of a Palladium Foil with NO 2",
abstract = " Abstract: The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO 2 pressures of 10 –6 , 10 –5 , and 10 –4 mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3d 5/2 , Pd 3p 3/2 , and O 1s binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness d was estimated based on the weakening of the Pd 3d line of metallic palladium. As the interaction temperature was increased, d initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state. ",
keywords = "NO, palladium, PdO, X-ray photoelectron spectroscopy (XPS), OXIDE, CATALYTIC-REDUCTION, IN-SITU XPS, CO, NO2, METHANE, PD, RAY PHOTOELECTRON-SPECTROSCOPY, PD(111) OXIDATION, SURFACE, NITROGEN-DIOXIDE",
author = "Smirnov, {M. Yu} and Klembovskii, {I. O.} and Kalinkin, {A. V.} and Bukhtiyarov, {V. I.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = nov,
day = "1",
doi = "10.1134/S0023158418060150",
language = "English",
volume = "59",
pages = "786--791",
journal = "Kinetics and Catalysis",
issn = "0023-1584",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "6",

}

RIS

TY - JOUR

T1 - An XPS Study of the Interaction of a Palladium Foil with NO 2

AU - Smirnov, M. Yu

AU - Klembovskii, I. O.

AU - Kalinkin, A. V.

AU - Bukhtiyarov, V. I.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - Abstract: The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO 2 pressures of 10 –6 , 10 –5 , and 10 –4 mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3d 5/2 , Pd 3p 3/2 , and O 1s binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness d was estimated based on the weakening of the Pd 3d line of metallic palladium. As the interaction temperature was increased, d initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state.

AB - Abstract: The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO 2 pressures of 10 –6 , 10 –5 , and 10 –4 mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3d 5/2 , Pd 3p 3/2 , and O 1s binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness d was estimated based on the weakening of the Pd 3d line of metallic palladium. As the interaction temperature was increased, d initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state.

KW - NO

KW - palladium

KW - PdO

KW - X-ray photoelectron spectroscopy (XPS)

KW - OXIDE

KW - CATALYTIC-REDUCTION

KW - IN-SITU XPS

KW - CO

KW - NO2

KW - METHANE

KW - PD

KW - RAY PHOTOELECTRON-SPECTROSCOPY

KW - PD(111) OXIDATION

KW - SURFACE

KW - NITROGEN-DIOXIDE

UR - http://www.scopus.com/inward/record.url?scp=85062629033&partnerID=8YFLogxK

U2 - 10.1134/S0023158418060150

DO - 10.1134/S0023158418060150

M3 - Article

AN - SCOPUS:85062629033

VL - 59

SP - 786

EP - 791

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 6

ER -

ID: 18808575