Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review
An insight into the gas-phase inhibition mechanism of polymers by addition of triphenyl phosphate flame retardant. / Trubachev, S. A.; Korobeinichev, O. P.; Kostritsa, S. A. et al.
International Conference on Physics and Chemistry of Combustion and Processes in Extreme Environments, ComPhysChem 20-21 and VI International Summer School "Modern Quantum Chemistry Methods in Applications". ed. / Valeriy N. Azyazov; Alexander M. Mebel. American Institute of Physics Inc., 2020. 0033887 (AIP Conference Proceedings; Vol. 2304).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review
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TY - GEN
T1 - An insight into the gas-phase inhibition mechanism of polymers by addition of triphenyl phosphate flame retardant
AU - Trubachev, S. A.
AU - Korobeinichev, O. P.
AU - Kostritsa, S. A.
AU - Kobtsev, V. D.
AU - Paletsky, A. A.
AU - Kumar, Amit
AU - Smirnov, V. V.
N1 - Funding Information: This work was supported by the Russian Foundation for Basic Research (Project No.19-03-00611). Publisher Copyright: © 2020 Author(s). Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/12/8
Y1 - 2020/12/8
N2 - In our work, we studied the effect of the triphenyl phosphate flame retardant (TPP) on the flammability of polymethyl methacrylate (PMMA) using probe (microthermocouples) and non-disturbing planar laser-induced fluorescence (PLIF) diagnostic methods. Addition of TPP results in a decrease of the burning rate, reduction of the size of the pyrolysis zone, abatement of the heat flux from the flame to the polymer surface, and also decrease in the concentration of OH radicals in the flame, leading to quenching. Thus, the gas-phase effect of the TPP flame retardant on the flammability of the PMMA polymer was demonstrated.
AB - In our work, we studied the effect of the triphenyl phosphate flame retardant (TPP) on the flammability of polymethyl methacrylate (PMMA) using probe (microthermocouples) and non-disturbing planar laser-induced fluorescence (PLIF) diagnostic methods. Addition of TPP results in a decrease of the burning rate, reduction of the size of the pyrolysis zone, abatement of the heat flux from the flame to the polymer surface, and also decrease in the concentration of OH radicals in the flame, leading to quenching. Thus, the gas-phase effect of the TPP flame retardant on the flammability of the PMMA polymer was demonstrated.
UR - http://www.scopus.com/inward/record.url?scp=85097998397&partnerID=8YFLogxK
U2 - 10.1063/5.0033887
DO - 10.1063/5.0033887
M3 - Conference contribution
AN - SCOPUS:85097998397
T3 - AIP Conference Proceedings
BT - International Conference on Physics and Chemistry of Combustion and Processes in Extreme Environments, ComPhysChem 20-21 and VI International Summer School "Modern Quantum Chemistry Methods in Applications"
A2 - Azyazov, Valeriy N.
A2 - Mebel, Alexander M.
PB - American Institute of Physics Inc.
T2 - 2nd International Conference on Physics and Chemistry of Combustion and Processes in Extreme Environments, ComPhysChem 20-21 and 6th International Summer School on Modern Quantum Chemistry Methods in Applications
Y2 - 26 July 2021 through 30 July 2021
ER -
ID: 27342645