Research output: Contribution to journal › Article › peer-review
Adsorption and Textural Properties of LSX Zeolite at the Initial Stages of Destruction. / Leonova, A. A.; Ayupov, A. B.; Fenelonov, V. B. et al.
In: Protection of Metals and Physical Chemistry of Surfaces, Vol. 53, No. 6, 01.11.2017, p. 989-994.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Adsorption and Textural Properties of LSX Zeolite at the Initial Stages of Destruction
AU - Leonova, A. A.
AU - Ayupov, A. B.
AU - Fenelonov, V. B.
AU - Mel’gunov, M. S.
N1 - Publisher Copyright: © 2017, Pleiades Publishing, Ltd.
PY - 2017/11/1
Y1 - 2017/11/1
N2 - Alteration of adsorption properties and porous structure (texture) of the KNaLSX zeolite at the initial stages of its destruction during ion-exchange modification in solutions of NH4Cl and thermal shock under vacuum degassing has been studied. Transmission electron microscopy, X-ray diffraction, low-temperature nitrogen adsorption and adsorption of CO2 and CH4 at 273 K were applied for characterization of the obtained materials. Conversion of the predominantly microporous material to the material with threemode pore-size distribution is shown. Significant fraction of the faujasite phase and corresponding micropores are preserved in the material. This is accompanied with formation of pores of two types: quasi-spherical mesopores with the characteristic size of 5 nm and the meso-macropores with typical size exceeding 40 nm. Basing on the obtained results, a mechanism of textural changes in the LSX zeolite treated under applied conditions is proposed.
AB - Alteration of adsorption properties and porous structure (texture) of the KNaLSX zeolite at the initial stages of its destruction during ion-exchange modification in solutions of NH4Cl and thermal shock under vacuum degassing has been studied. Transmission electron microscopy, X-ray diffraction, low-temperature nitrogen adsorption and adsorption of CO2 and CH4 at 273 K were applied for characterization of the obtained materials. Conversion of the predominantly microporous material to the material with threemode pore-size distribution is shown. Significant fraction of the faujasite phase and corresponding micropores are preserved in the material. This is accompanied with formation of pores of two types: quasi-spherical mesopores with the characteristic size of 5 nm and the meso-macropores with typical size exceeding 40 nm. Basing on the obtained results, a mechanism of textural changes in the LSX zeolite treated under applied conditions is proposed.
KW - CO and CH adsorption
KW - LSX zeolite
KW - mechanism of mesopores’ formation
KW - NaCl ion exchange
KW - NHCl ion exchange
UR - http://www.scopus.com/inward/record.url?scp=85044076312&partnerID=8YFLogxK
U2 - 10.1134/S2070205117060168
DO - 10.1134/S2070205117060168
M3 - Article
AN - SCOPUS:85044076312
VL - 53
SP - 989
EP - 994
JO - Protection of Metals and Physical Chemistry of Surfaces
JF - Protection of Metals and Physical Chemistry of Surfaces
SN - 2070-2051
IS - 6
ER -
ID: 12179088