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Adducts of the Zinc Salt of Dinitramic Acid. / Il'yasov, Sergey G; Glukhacheva, Vera S; Il'yasov, Dmitri S et al.

In: Materials, Vol. 16, No. 1, 70, 01.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Il'yasov, SG, Glukhacheva, VS, Il'yasov, DS, Zhukov, EE, Eltsov, IV, Nefedov, AA & Gatilov, YV 2023, 'Adducts of the Zinc Salt of Dinitramic Acid', Materials, vol. 16, no. 1, 70. https://doi.org/10.3390/ma16010070

APA

Il'yasov, S. G., Glukhacheva, V. S., Il'yasov, D. S., Zhukov, E. E., Eltsov, I. V., Nefedov, A. A., & Gatilov, Y. V. (2023). Adducts of the Zinc Salt of Dinitramic Acid. Materials, 16(1), [70]. https://doi.org/10.3390/ma16010070

Vancouver

Il'yasov SG, Glukhacheva VS, Il'yasov DS, Zhukov EE, Eltsov IV, Nefedov AA et al. Adducts of the Zinc Salt of Dinitramic Acid. Materials. 2023 Jan;16(1):70. Epub 2022 Dec 21. doi: 10.3390/ma16010070

Author

Il'yasov, Sergey G ; Glukhacheva, Vera S ; Il'yasov, Dmitri S et al. / Adducts of the Zinc Salt of Dinitramic Acid. In: Materials. 2023 ; Vol. 16, No. 1.

BibTeX

@article{03b31b1db8fd4ca8802f8fd1c0dae4d7,
title = "Adducts of the Zinc Salt of Dinitramic Acid",
abstract = "Herein, we describe the synthesis of coordination compounds starting from carbohydrazide ((H2NHN)2C=O (CHZ)) and the Zn2+ salt of dinitramic acid (HDN), which are high-nitrogen substances that exhibit properties similar to those of a burning-rate inhibitor of pyrotechnic compositions. This study demonstrates that these compounds react with glyoxal to furnish adducts of metal-organic macrocyclic cages bearing the elements of carbohydrazide, complexing metals and the HDN anion, depending on the ratio of the starting reactants. The assembled macrocyclic cage has {"}host-guest{"} properties and is a safe container for the storage of HDN salts. X-ray crystallographic analysis of the resultant coordination compound, [Zn(chz)3(N(NO2)2)2]), indicated that the metal-ligand association occurs via the N and O atoms of carbohydrazide. The zinc salt of dinitramic acid, which is enclosed into adducts with a macrocycle, is thermally stable and insensitive to mechanical impacts. The complex zinc salt of dinitramide was shown herein to exhibit inhibitory activity towards the burning rate of pyrotechnic compositions.",
keywords = "adducts, carbohydrazide, dinitramide, glyoxal, macrocycles, zinc (II)",
author = "Il'yasov, {Sergey G} and Glukhacheva, {Vera S} and Il'yasov, {Dmitri S} and Zhukov, {Egor E} and Eltsov, {Ilia V} and Nefedov, {Andrey A} and Gatilov, {Yuri V}",
note = "Funding: This research was supported by the Ministry of Science and Higher Education of the Russian Federation (agreement no. 075-15-2020-803 with the Zelinsky Institute of Organic Chemistry of the RAS).",
year = "2023",
month = jan,
doi = "10.3390/ma16010070",
language = "English",
volume = "16",
journal = "Materials",
issn = "1996-1944",
publisher = "MDPI AG",
number = "1",

}

RIS

TY - JOUR

T1 - Adducts of the Zinc Salt of Dinitramic Acid

AU - Il'yasov, Sergey G

AU - Glukhacheva, Vera S

AU - Il'yasov, Dmitri S

AU - Zhukov, Egor E

AU - Eltsov, Ilia V

AU - Nefedov, Andrey A

AU - Gatilov, Yuri V

N1 - Funding: This research was supported by the Ministry of Science and Higher Education of the Russian Federation (agreement no. 075-15-2020-803 with the Zelinsky Institute of Organic Chemistry of the RAS).

PY - 2023/1

Y1 - 2023/1

N2 - Herein, we describe the synthesis of coordination compounds starting from carbohydrazide ((H2NHN)2C=O (CHZ)) and the Zn2+ salt of dinitramic acid (HDN), which are high-nitrogen substances that exhibit properties similar to those of a burning-rate inhibitor of pyrotechnic compositions. This study demonstrates that these compounds react with glyoxal to furnish adducts of metal-organic macrocyclic cages bearing the elements of carbohydrazide, complexing metals and the HDN anion, depending on the ratio of the starting reactants. The assembled macrocyclic cage has "host-guest" properties and is a safe container for the storage of HDN salts. X-ray crystallographic analysis of the resultant coordination compound, [Zn(chz)3(N(NO2)2)2]), indicated that the metal-ligand association occurs via the N and O atoms of carbohydrazide. The zinc salt of dinitramic acid, which is enclosed into adducts with a macrocycle, is thermally stable and insensitive to mechanical impacts. The complex zinc salt of dinitramide was shown herein to exhibit inhibitory activity towards the burning rate of pyrotechnic compositions.

AB - Herein, we describe the synthesis of coordination compounds starting from carbohydrazide ((H2NHN)2C=O (CHZ)) and the Zn2+ salt of dinitramic acid (HDN), which are high-nitrogen substances that exhibit properties similar to those of a burning-rate inhibitor of pyrotechnic compositions. This study demonstrates that these compounds react with glyoxal to furnish adducts of metal-organic macrocyclic cages bearing the elements of carbohydrazide, complexing metals and the HDN anion, depending on the ratio of the starting reactants. The assembled macrocyclic cage has "host-guest" properties and is a safe container for the storage of HDN salts. X-ray crystallographic analysis of the resultant coordination compound, [Zn(chz)3(N(NO2)2)2]), indicated that the metal-ligand association occurs via the N and O atoms of carbohydrazide. The zinc salt of dinitramic acid, which is enclosed into adducts with a macrocycle, is thermally stable and insensitive to mechanical impacts. The complex zinc salt of dinitramide was shown herein to exhibit inhibitory activity towards the burning rate of pyrotechnic compositions.

KW - adducts

KW - carbohydrazide

KW - dinitramide

KW - glyoxal

KW - macrocycles

KW - zinc (II)

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85145647166&origin=inward&txGid=ec7b4a4ae7366352920d70a0659f2300

UR - https://www.mendeley.com/catalogue/f9cfee9f-3f2a-35d4-a91b-2979433c285c/

U2 - 10.3390/ma16010070

DO - 10.3390/ma16010070

M3 - Article

C2 - 36614408

VL - 16

JO - Materials

JF - Materials

SN - 1996-1944

IS - 1

M1 - 70

ER -

ID: 42508087