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Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether. / Topchiyan, P. A.; Vasilchenko, D. B.; Baidina, I. A. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 9, 01.09.2020, p. 1422-1431.

Research output: Contribution to journal › Article › peer-review

Harvard

Topchiyan, PA, Vasilchenko, DB, Baidina, IA & Korolkov, IV 2020, 'Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether', Journal of Structural Chemistry, vol. 61, no. 9, pp. 1422-1431. https://doi.org/10.1134/S0022476620090097

APA

Topchiyan, P. A., Vasilchenko, D. B., Baidina, I. A., & Korolkov, I. V. (2020). Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether. Journal of Structural Chemistry, 61(9), 1422-1431. https://doi.org/10.1134/S0022476620090097

Vancouver

Topchiyan PA, Vasilchenko DB, Baidina IA, Korolkov IV. Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether. Journal of Structural Chemistry. 2020 Sept 1;61(9):1422-1431. doi: 10.1134/S0022476620090097

Author

Topchiyan, P. A. ; Vasilchenko, D. B. ; Baidina, I. A. et al. / Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 9. pp. 1422-1431.

BibTeX

@article{a60f49bb426a4fafa7295ea3f3f20cbb,
title = "Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether",
abstract = "The possibility of isolating platinum(IV) nitrate complexes to the solid phase from a nitric acid solution of platinum in the form of adducts with dibenzo-18-crown-6, 15-crown-5, and 12-crown-4 ether is studied. It is found that when nitric acid solutions containing 15-crown-5 ether (15-C-5) are evaporated, a polycrystalline product consisting of mainly a mixture of phases with the compositions (H3O⊂15-C-5)2[Pt(NO3)6] (1), (H3O⊂15-C-5)2(15-C-5)[Pt(NO3)6]·2H2O (2), and (15-C-5)[Pt4(μ3-OH)2(μ2-OH)4(NO3)10]·3H2O (3) is formed. The structure of the mentioned compounds is established by single crystal X-ray diffraction. In the case of dibenzo-18-crown-6 ether, the interaction with a nitric acid solution of platinum results in the formation of a poorly soluble tetranitro derivative of macrocyclic ether. Evaporation of nitric acid solutions of platinum containing 12-crown-4 ether does not allow the preparation of a solid crystalline phase. [MediaObject not available: see fulltext.]",
keywords = "crown ethers, nitrate complexes, platinum, single crystal X-ray diffraction analysis, CO OXIDATION",
author = "Topchiyan, {P. A.} and Vasilchenko, {D. B.} and Baidina, {I. A.} and Korolkov, {I. V.}",
year = "2020",
month = sep,
day = "1",
doi = "10.1134/S0022476620090097",
language = "English",
volume = "61",
pages = "1422--1431",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "9",

}

RIS

TY - JOUR

T1 - Adducts of platinum(IV) nitrate complexes with 15-crown-5 ether

AU - Topchiyan, P. A.

AU - Vasilchenko, D. B.

AU - Baidina, I. A.

AU - Korolkov, I. V.

PY - 2020/9/1

Y1 - 2020/9/1

N2 - The possibility of isolating platinum(IV) nitrate complexes to the solid phase from a nitric acid solution of platinum in the form of adducts with dibenzo-18-crown-6, 15-crown-5, and 12-crown-4 ether is studied. It is found that when nitric acid solutions containing 15-crown-5 ether (15-C-5) are evaporated, a polycrystalline product consisting of mainly a mixture of phases with the compositions (H3O⊂15-C-5)2[Pt(NO3)6] (1), (H3O⊂15-C-5)2(15-C-5)[Pt(NO3)6]·2H2O (2), and (15-C-5)[Pt4(μ3-OH)2(μ2-OH)4(NO3)10]·3H2O (3) is formed. The structure of the mentioned compounds is established by single crystal X-ray diffraction. In the case of dibenzo-18-crown-6 ether, the interaction with a nitric acid solution of platinum results in the formation of a poorly soluble tetranitro derivative of macrocyclic ether. Evaporation of nitric acid solutions of platinum containing 12-crown-4 ether does not allow the preparation of a solid crystalline phase. [MediaObject not available: see fulltext.]

AB - The possibility of isolating platinum(IV) nitrate complexes to the solid phase from a nitric acid solution of platinum in the form of adducts with dibenzo-18-crown-6, 15-crown-5, and 12-crown-4 ether is studied. It is found that when nitric acid solutions containing 15-crown-5 ether (15-C-5) are evaporated, a polycrystalline product consisting of mainly a mixture of phases with the compositions (H3O⊂15-C-5)2[Pt(NO3)6] (1), (H3O⊂15-C-5)2(15-C-5)[Pt(NO3)6]·2H2O (2), and (15-C-5)[Pt4(μ3-OH)2(μ2-OH)4(NO3)10]·3H2O (3) is formed. The structure of the mentioned compounds is established by single crystal X-ray diffraction. In the case of dibenzo-18-crown-6 ether, the interaction with a nitric acid solution of platinum results in the formation of a poorly soluble tetranitro derivative of macrocyclic ether. Evaporation of nitric acid solutions of platinum containing 12-crown-4 ether does not allow the preparation of a solid crystalline phase. [MediaObject not available: see fulltext.]

KW - crown ethers

KW - nitrate complexes

KW - platinum

KW - single crystal X-ray diffraction analysis

KW - CO OXIDATION

UR - http://www.scopus.com/inward/record.url?scp=85092594411&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/83d4940d-399a-3682-a82b-6f4377d9eac7/

U2 - 10.1134/S0022476620090097

DO - 10.1134/S0022476620090097

M3 - Article

AN - SCOPUS:85092594411

VL - 61

SP - 1422

EP - 1431

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 9

ER -

ID: 25689234