Standard

Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol. / Smirnov, Andrey A.; Selishcheva, Svetlana A.; Yakovlev, Vadim A.

In: Catalysts, Vol. 8, No. 12, 595, 01.12.2018.

Research output: Contribution to journal › Review article › peer-review

Harvard

Smirnov, AA, Selishcheva, SA & Yakovlev, VA 2018, 'Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol', Catalysts, vol. 8, no. 12, 595. https://doi.org/10.3390/catal8120595

APA

Smirnov, A. A., Selishcheva, S. A., & Yakovlev, V. A. (2018). Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol. Catalysts, 8(12), [595]. https://doi.org/10.3390/catal8120595

Vancouver

Smirnov AA, Selishcheva SA, Yakovlev VA. Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol. Catalysts. 2018 Dec 1;8(12):595. doi: 10.3390/catal8120595

Author

Smirnov, Andrey A. ; Selishcheva, Svetlana A. ; Yakovlev, Vadim A. / Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol. In: Catalysts. 2018 ; Vol. 8, No. 12.

BibTeX

@article{fd9c9c938d4c4c32b5b0208d5cd60292,
title = "Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol",
abstract = "Biodiesel is one of the most attractive sources of clean energy. It is produced by the transformation of vegetable oils with up to 10% formation of glycerol as a by-product. Therefore, development of new approaches for processing bio-glycerol into such value-added chemical compounds as solketals is necessary. Thus, various six-and five-membered cyclic compounds can be prepared by acetalization of glycerol with aldehyde or ketone. The resulting glycerol oxygenates are excellent fuel additives that increase viscosity, octane or cetane number, and stability to oxidation. In addition, these products significantly reduce carbon monoxide emissions from standard diesel fuel. In this review, we highlight recent advances in the glycerol valorization for the sustainable production of bio-additives. The review includes a discussion of the innovative and potential catalysts to produce solketals.",
keywords = "Acetal, Acetalization, Fuel additives, Glycerol, Ketal",
author = "Smirnov, {Andrey A.} and Selishcheva, {Svetlana A.} and Yakovlev, {Vadim A.}",
note = "Funding Information: Funding: This work was conducted within the framework of budget project No. AAAA-A17-117041710075-0 for Boreskov Institute of Catalysis",
year = "2018",
month = dec,
day = "1",
doi = "10.3390/catal8120595",
language = "English",
volume = "8",
journal = "Catalysts",
issn = "2073-4344",
publisher = "MDPI AG",
number = "12",

}

RIS

TY - JOUR

T1 - Acetalization catalysts for synthesis of valuable oxygenated fuel additives from glycerol

AU - Smirnov, Andrey A.

AU - Selishcheva, Svetlana A.

AU - Yakovlev, Vadim A.

N1 - Funding Information: Funding: This work was conducted within the framework of budget project No. AAAA-A17-117041710075-0 for Boreskov Institute of Catalysis

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Biodiesel is one of the most attractive sources of clean energy. It is produced by the transformation of vegetable oils with up to 10% formation of glycerol as a by-product. Therefore, development of new approaches for processing bio-glycerol into such value-added chemical compounds as solketals is necessary. Thus, various six-and five-membered cyclic compounds can be prepared by acetalization of glycerol with aldehyde or ketone. The resulting glycerol oxygenates are excellent fuel additives that increase viscosity, octane or cetane number, and stability to oxidation. In addition, these products significantly reduce carbon monoxide emissions from standard diesel fuel. In this review, we highlight recent advances in the glycerol valorization for the sustainable production of bio-additives. The review includes a discussion of the innovative and potential catalysts to produce solketals.

AB - Biodiesel is one of the most attractive sources of clean energy. It is produced by the transformation of vegetable oils with up to 10% formation of glycerol as a by-product. Therefore, development of new approaches for processing bio-glycerol into such value-added chemical compounds as solketals is necessary. Thus, various six-and five-membered cyclic compounds can be prepared by acetalization of glycerol with aldehyde or ketone. The resulting glycerol oxygenates are excellent fuel additives that increase viscosity, octane or cetane number, and stability to oxidation. In addition, these products significantly reduce carbon monoxide emissions from standard diesel fuel. In this review, we highlight recent advances in the glycerol valorization for the sustainable production of bio-additives. The review includes a discussion of the innovative and potential catalysts to produce solketals.

KW - Acetal

KW - Acetalization

KW - Fuel additives

KW - Glycerol

KW - Ketal

UR - http://www.scopus.com/inward/record.url?scp=85062407739&partnerID=8YFLogxK

U2 - 10.3390/catal8120595

DO - 10.3390/catal8120595

M3 - Review article

AN - SCOPUS:85062407739

VL - 8

JO - Catalysts

JF - Catalysts

SN - 2073-4344

IS - 12

M1 - 595

ER -

ID: 26147551