Standard

Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation. / Zhdanov, Ravil K.; Gets, Kirill V.; Bozhko, Yulia Y. et al.

In: Surfaces and Interfaces, Vol. 43, 103549, 12.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Zhdanov, RK, Gets, KV, Bozhko, YY & Belosludov, VR 2023, 'Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation', Surfaces and Interfaces, vol. 43, 103549. https://doi.org/10.1016/j.surfin.2023.103549

APA

Zhdanov, R. K., Gets, K. V., Bozhko, Y. Y., & Belosludov, V. R. (2023). Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation. Surfaces and Interfaces, 43, [103549]. https://doi.org/10.1016/j.surfin.2023.103549

Vancouver

Zhdanov RK, Gets KV, Bozhko YY, Belosludov VR. Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation. Surfaces and Interfaces. 2023 Dec;43:103549. doi: 10.1016/j.surfin.2023.103549

Author

Zhdanov, Ravil K. ; Gets, Kirill V. ; Bozhko, Yulia Y. et al. / Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation. In: Surfaces and Interfaces. 2023 ; Vol. 43.

BibTeX

@article{469e633aa39b43e7afe9c4d8093ed093,
title = "Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation",
abstract = "This paper reports theoretical study of stability zones and composition of “H2 + CO2” clathrate hydrates of cubic structure I (sI) and II (sII) in dependence on pressure and temperature for different gas phase composition using extended van der Waals and Platteeuw statistical thermodynamic model. It was found that rising of CO2 content in H2 + CO2 gas mixture phase makes formation of sI hydrate more thermodynamically preferable rather than sII hydrate, and in the same time CO2 content increasing reduces formation pressure of the resulting hydrate. Observed difference between gas phase composition and gas molecules trapped in hydrate phase allows to consider these hydrates as a gas separation medium. We believe that presented results could be applicable for improvements of hydrate technology for CO2 utilization as a greenhouse gas, and hydrogen obtained from natural gas refinement transportation.",
keywords = "Carbon dioxide, Gas hydrates, Hydrogen, Statistical-thermodynamic theory",
author = "Zhdanov, {Ravil K.} and Gets, {Kirill V.} and Bozhko, {Yulia Y.} and Belosludov, {Vladimir R.}",
note = "This work is supported by RSF project No 22-19-00428 .",
year = "2023",
month = dec,
doi = "10.1016/j.surfin.2023.103549",
language = "English",
volume = "43",
journal = "Surfaces and Interfaces",
issn = "2468-0230",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Accurate description of gas hydrates of carbon dioxide and hydrogen for storage and transportation

AU - Zhdanov, Ravil K.

AU - Gets, Kirill V.

AU - Bozhko, Yulia Y.

AU - Belosludov, Vladimir R.

N1 - This work is supported by RSF project No 22-19-00428 .

PY - 2023/12

Y1 - 2023/12

N2 - This paper reports theoretical study of stability zones and composition of “H2 + CO2” clathrate hydrates of cubic structure I (sI) and II (sII) in dependence on pressure and temperature for different gas phase composition using extended van der Waals and Platteeuw statistical thermodynamic model. It was found that rising of CO2 content in H2 + CO2 gas mixture phase makes formation of sI hydrate more thermodynamically preferable rather than sII hydrate, and in the same time CO2 content increasing reduces formation pressure of the resulting hydrate. Observed difference between gas phase composition and gas molecules trapped in hydrate phase allows to consider these hydrates as a gas separation medium. We believe that presented results could be applicable for improvements of hydrate technology for CO2 utilization as a greenhouse gas, and hydrogen obtained from natural gas refinement transportation.

AB - This paper reports theoretical study of stability zones and composition of “H2 + CO2” clathrate hydrates of cubic structure I (sI) and II (sII) in dependence on pressure and temperature for different gas phase composition using extended van der Waals and Platteeuw statistical thermodynamic model. It was found that rising of CO2 content in H2 + CO2 gas mixture phase makes formation of sI hydrate more thermodynamically preferable rather than sII hydrate, and in the same time CO2 content increasing reduces formation pressure of the resulting hydrate. Observed difference between gas phase composition and gas molecules trapped in hydrate phase allows to consider these hydrates as a gas separation medium. We believe that presented results could be applicable for improvements of hydrate technology for CO2 utilization as a greenhouse gas, and hydrogen obtained from natural gas refinement transportation.

KW - Carbon dioxide

KW - Gas hydrates

KW - Hydrogen

KW - Statistical-thermodynamic theory

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85176470762&origin=inward&txGid=13e713828694fc140189f161a0b59f9c

UR - https://www.mendeley.com/catalogue/66ec17e7-0648-33aa-8fb4-0dbaed917f5b/

U2 - 10.1016/j.surfin.2023.103549

DO - 10.1016/j.surfin.2023.103549

M3 - Article

VL - 43

JO - Surfaces and Interfaces

JF - Surfaces and Interfaces

SN - 2468-0230

M1 - 103549

ER -

ID: 59286206