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A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates. / Turgambaeva, A. E.; Zherikova, K. V.; Mosyagina, S. A. et al.

In: Russian Journal of Applied Chemistry, Vol. 90, No. 7, 01.07.2017, p. 1062-1067.

Research output: Contribution to journalArticlepeer-review

Harvard

Turgambaeva, AE, Zherikova, KV, Mosyagina, SA & Igumenov, IK 2017, 'A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates', Russian Journal of Applied Chemistry, vol. 90, no. 7, pp. 1062-1067. https://doi.org/10.1134/S1070427217070060

APA

Turgambaeva, A. E., Zherikova, K. V., Mosyagina, S. A., & Igumenov, I. K. (2017). A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates. Russian Journal of Applied Chemistry, 90(7), 1062-1067. https://doi.org/10.1134/S1070427217070060

Vancouver

Turgambaeva AE, Zherikova KV, Mosyagina SA, Igumenov IK. A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates. Russian Journal of Applied Chemistry. 2017 Jul 1;90(7):1062-1067. doi: 10.1134/S1070427217070060

Author

Turgambaeva, A. E. ; Zherikova, K. V. ; Mosyagina, S. A. et al. / A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates. In: Russian Journal of Applied Chemistry. 2017 ; Vol. 90, No. 7. pp. 1062-1067.

BibTeX

@article{693499024f4f4e709e9b8afa522f8db7,
title = "A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates",
abstract = "TG-DTA method was used to study the thermal behavior of the Zr(thd)4/[Nd(thd)3]2 system (thd = 2,2,6.6-tetramethylheptane-3,5-dionato) in the condensed phase. Data were obtained on the kinetics of vaporization of individual beta-diketonate precursors and variously prepared mixtures. A mass-spectrometric monitoring of the gas-phase composition was employed to examine the thermal stability of vapors and to study in situ how individual dipyvaloylmethanates Zr(thd)4 and Nd(thd)3 and the two-component system Zr(thd)4–Nd(thd)3 are thermally decomposed in a vacuum and in the presence of oxygen. It was found that there is no chemical interaction between the precursors in the whole temperature range under study, but rather pronounced effects of nonadditivity of the thermal parameters are observed for the mixtures examined.",
author = "Turgambaeva, {A. E.} and Zherikova, {K. V.} and Mosyagina, {S. A.} and Igumenov, {I. K.}",
year = "2017",
month = jul,
day = "1",
doi = "10.1134/S1070427217070060",
language = "English",
volume = "90",
pages = "1062--1067",
journal = "Russian Journal of Applied Chemistry",
issn = "1070-4272",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - A study of the thermal behavior of the system of zirconium and neodymium dipyvaloylmethanates

AU - Turgambaeva, A. E.

AU - Zherikova, K. V.

AU - Mosyagina, S. A.

AU - Igumenov, I. K.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - TG-DTA method was used to study the thermal behavior of the Zr(thd)4/[Nd(thd)3]2 system (thd = 2,2,6.6-tetramethylheptane-3,5-dionato) in the condensed phase. Data were obtained on the kinetics of vaporization of individual beta-diketonate precursors and variously prepared mixtures. A mass-spectrometric monitoring of the gas-phase composition was employed to examine the thermal stability of vapors and to study in situ how individual dipyvaloylmethanates Zr(thd)4 and Nd(thd)3 and the two-component system Zr(thd)4–Nd(thd)3 are thermally decomposed in a vacuum and in the presence of oxygen. It was found that there is no chemical interaction between the precursors in the whole temperature range under study, but rather pronounced effects of nonadditivity of the thermal parameters are observed for the mixtures examined.

AB - TG-DTA method was used to study the thermal behavior of the Zr(thd)4/[Nd(thd)3]2 system (thd = 2,2,6.6-tetramethylheptane-3,5-dionato) in the condensed phase. Data were obtained on the kinetics of vaporization of individual beta-diketonate precursors and variously prepared mixtures. A mass-spectrometric monitoring of the gas-phase composition was employed to examine the thermal stability of vapors and to study in situ how individual dipyvaloylmethanates Zr(thd)4 and Nd(thd)3 and the two-component system Zr(thd)4–Nd(thd)3 are thermally decomposed in a vacuum and in the presence of oxygen. It was found that there is no chemical interaction between the precursors in the whole temperature range under study, but rather pronounced effects of nonadditivity of the thermal parameters are observed for the mixtures examined.

UR - http://www.scopus.com/inward/record.url?scp=85034236138&partnerID=8YFLogxK

U2 - 10.1134/S1070427217070060

DO - 10.1134/S1070427217070060

M3 - Article

AN - SCOPUS:85034236138

VL - 90

SP - 1062

EP - 1067

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

SN - 1070-4272

IS - 7

ER -

ID: 10066755