Research output: Contribution to journal › Article › peer-review
A Series of Coordination Polymers Based on 4,8-Disulfo-2,6-Naphthalenedicarboxylic Acid. / Zhukov, L. A.; Lysova, A. A.; Samsonenko, D. G. et al.
In: Journal of Structural Chemistry, Vol. 65, No. 10, 10.2024, p. 2111-2120.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - A Series of Coordination Polymers Based on 4,8-Disulfo-2,6-Naphthalenedicarboxylic Acid
AU - Zhukov, L. A.
AU - Lysova, A. A.
AU - Samsonenko, D. G.
AU - Dybtsev, D. N.
AU - Fedin, V. P.
N1 - The work was supported by the Russian Science Foundation (grant No. 23-13-00310, https://rscf.ru/project 23-13-00310).
PY - 2024/10
Y1 - 2024/10
N2 - Abstract: Five new metal-organic frameworks based on 4,8-disulfo-2,6-naphthalenedicarboxylic acid (H4dsndc) are obtained: [Cd2(dsndc)(dmf)6] (1), [Mn2(dsndc)(dmf)6] (2), [Zn2(dsndc)(dmf)6] (3), [Co2(dsndc)(dmf)6] (4), and [Cd2(dsndc)(dma)6] (5) (DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide). The four of them (1–4) are isostructural layered coordination polymers. The structures of all compounds are determined by the single crystal X-ray diffraction analysis. Compounds 1–3 and 5 are obtained as chemically and phase-pure and are characterized by the standard complex of physicochemical techniques (powder XRD, IR, TGA, and CHN). Photoluminescence excitation and emission spectra are recorded for compound 3, and a quantum yield of 18% is obtained.
AB - Abstract: Five new metal-organic frameworks based on 4,8-disulfo-2,6-naphthalenedicarboxylic acid (H4dsndc) are obtained: [Cd2(dsndc)(dmf)6] (1), [Mn2(dsndc)(dmf)6] (2), [Zn2(dsndc)(dmf)6] (3), [Co2(dsndc)(dmf)6] (4), and [Cd2(dsndc)(dma)6] (5) (DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide). The four of them (1–4) are isostructural layered coordination polymers. The structures of all compounds are determined by the single crystal X-ray diffraction analysis. Compounds 1–3 and 5 are obtained as chemically and phase-pure and are characterized by the standard complex of physicochemical techniques (powder XRD, IR, TGA, and CHN). Photoluminescence excitation and emission spectra are recorded for compound 3, and a quantum yield of 18% is obtained.
KW - 4,8-disulfo-2,6-naphthalenedicarboxylic acid
KW - metal-organic frameworks
KW - photoluminescence
KW - single crystal X-ray diffraction analysis
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85209787879&origin=inward&txGid=01e54f33db9eff7cd56fea20f413882c
UR - https://www.mendeley.com/catalogue/85b9e284-3a61-338d-86ed-c0382abbfc63/
U2 - 10.1134/S0022476624100196
DO - 10.1134/S0022476624100196
M3 - Article
VL - 65
SP - 2111
EP - 2120
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 10
ER -
ID: 61114983