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A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium. / Zonov, Ya V.; Karpov, V. M.; Mezhenkova, and T.V.

In: Russian Journal of General Chemistry, Vol. 95, No. 2, 26.03.2025, p. 374-382.

Research output: Contribution to journal › Article › peer-review

Harvard

Zonov, YV, Karpov, VM & Mezhenkova, ATV 2025, 'A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium', Russian Journal of General Chemistry, vol. 95, no. 2, pp. 374-382. https://doi.org/10.1134/S1070363225600286

APA

Zonov, Y. V., Karpov, V. M., & Mezhenkova, A. T. V. (2025). A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium. Russian Journal of General Chemistry, 95(2), 374-382. https://doi.org/10.1134/S1070363225600286

Vancouver

Zonov YV, Karpov VM, Mezhenkova ATV. A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium. Russian Journal of General Chemistry. 2025 Mar 26;95(2):374-382. doi: 10.1134/S1070363225600286

Author

Zonov, Ya V. ; Karpov, V. M. ; Mezhenkova, and T.V. / A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium. In: Russian Journal of General Chemistry. 2025 ; Vol. 95, No. 2. pp. 374-382.

BibTeX

@article{dcbffc08e3a94c4f832e31cc95f81d95,
title = "A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium",
abstract = "Abstract: 4-X-Perfluoroisopropylbenzenes (X = F, Cl, H, CH3) undergo carbonylation under the action of CO/SbF5 at room temperature and atmospheric pressure, forming 2-(4-X-tetrafluorophenyl)perfluoro-2-methylpropanoyl fluorides. Upon treatment with NH3/CH2Cl2, the latter are converted into amides of the corresponding carboxylic acids and their further transformation products under the action of ammonia—4-X-2,3,5,6-tetrafluoro-1-(1,1,1,3,3,3-hexafluoropropan-2-yl)benzenes. Perfluorinated p-cymene (X = CF3), p- and m-xylenes, as well as ethyl- and propylbenzenes, do not undergo carbonylation under the action of CO/SbF5.",
keywords = "antimony pentafluoride, carbon monoxide, carbonylation, isopropylbenzene, perfluorinated alkylbenzene",
author = "Zonov, {Ya V.} and Karpov, {V. M.} and Mezhenkova, {and T.V.}",
note = "Zonov, Ya. V. A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium / Ya. V. Zonov, V. M. Karpov, A. T. V. Mezhenkova // Russian Journal of General Chemistry. – 2025. – Vol. 95, No. 2. – P. 374-382. – DOI 10.1134/S1070363225600286.",
year = "2025",
month = mar,
day = "26",
doi = "10.1134/S1070363225600286",
language = "English",
volume = "95",
pages = "374--382",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "2",

}

RIS

TY - JOUR

T1 - A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium

AU - Zonov, Ya V.

AU - Karpov, V. M.

AU - Mezhenkova, and T.V.

N1 - Zonov, Ya. V. A Reaction of Perfluoroalkylbenzenes with Carbon Monoxide in Antimony Pentafluoride Medium / Ya. V. Zonov, V. M. Karpov, A. T. V. Mezhenkova // Russian Journal of General Chemistry. – 2025. – Vol. 95, No. 2. – P. 374-382. – DOI 10.1134/S1070363225600286.

PY - 2025/3/26

Y1 - 2025/3/26

N2 - Abstract: 4-X-Perfluoroisopropylbenzenes (X = F, Cl, H, CH3) undergo carbonylation under the action of CO/SbF5 at room temperature and atmospheric pressure, forming 2-(4-X-tetrafluorophenyl)perfluoro-2-methylpropanoyl fluorides. Upon treatment with NH3/CH2Cl2, the latter are converted into amides of the corresponding carboxylic acids and their further transformation products under the action of ammonia—4-X-2,3,5,6-tetrafluoro-1-(1,1,1,3,3,3-hexafluoropropan-2-yl)benzenes. Perfluorinated p-cymene (X = CF3), p- and m-xylenes, as well as ethyl- and propylbenzenes, do not undergo carbonylation under the action of CO/SbF5.

AB - Abstract: 4-X-Perfluoroisopropylbenzenes (X = F, Cl, H, CH3) undergo carbonylation under the action of CO/SbF5 at room temperature and atmospheric pressure, forming 2-(4-X-tetrafluorophenyl)perfluoro-2-methylpropanoyl fluorides. Upon treatment with NH3/CH2Cl2, the latter are converted into amides of the corresponding carboxylic acids and their further transformation products under the action of ammonia—4-X-2,3,5,6-tetrafluoro-1-(1,1,1,3,3,3-hexafluoropropan-2-yl)benzenes. Perfluorinated p-cymene (X = CF3), p- and m-xylenes, as well as ethyl- and propylbenzenes, do not undergo carbonylation under the action of CO/SbF5.

KW - antimony pentafluoride

KW - carbon monoxide

KW - carbonylation

KW - isopropylbenzene

KW - perfluorinated alkylbenzene

UR - https://www.mendeley.com/catalogue/b1b0c426-c86a-3fc6-b7c6-c1287d066872/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105000983973&origin=inward&txGid=3824c56fbe2df5dcaf0d327a79d1cfab

UR - https://elibrary.ru/item.asp?id=80504499

U2 - 10.1134/S1070363225600286

DO - 10.1134/S1070363225600286

M3 - Article

VL - 95

SP - 374

EP - 382

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 2

ER -

ID: 65132285