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A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]. / Marchuk, Margarita V.; Vorotnikov, Yuri A.; Ivanov, Anton A. et al.

In: Symmetry, Vol. 14, No. 10, 2117, 10.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Marchuk, MV, Vorotnikov, YA, Ivanov, AA, Eltsov, IV, Kuratieva, NV & Shestopalov, MA 2022, 'A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]', Symmetry, vol. 14, no. 10, 2117. https://doi.org/10.3390/sym14102117

APA

Marchuk, M. V., Vorotnikov, Y. A., Ivanov, A. A., Eltsov, I. V., Kuratieva, N. V., & Shestopalov, M. A. (2022). A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]. Symmetry, 14(10), [2117]. https://doi.org/10.3390/sym14102117

Vancouver

Marchuk MV, Vorotnikov YA, Ivanov AA, Eltsov IV, Kuratieva NV, Shestopalov MA. A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]. Symmetry. 2022 Oct;14(10):2117. doi: 10.3390/sym14102117

Author

Marchuk, Margarita V. ; Vorotnikov, Yuri A. ; Ivanov, Anton A. et al. / A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]. In: Symmetry. 2022 ; Vol. 14, No. 10.

BibTeX

@article{d8ad29667edb4f8494e52e63fb0ff998,
title = "A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]",
abstract = "Despite that the chemistry of octahedral cluster complexes has been actively developed recently, there are still a lot of unexplored areas. For example, to date, only a few halide M6-clusters with N-heterocycles are known. Here, we obtained an apically heteroleptic octahedral iodide molybdenum cluster complex with pyridine ligands—trans-[{Mo6I8}(py)2I4] by the direct substitution of iodide apical ligands of [{Mo6I8}I6]2– in a pyridine solution. The compound co-crystalized with a monosubstituted form [{Mo6I8}(py)I5]– in the ratio of 1:4, and thus, can be described by the formula (pyH)0.2[{Mo6I8}(py)1.8I4.2]·1.8py. The composition was studied using XRPD, elemental analyses, and 1H-NMR and IR spectroscopies. According to the absorption and luminescence data, the partial substitution of apical ligands weakly affects optical properties.",
keywords = "absorption, crystal structure, luminescence, octahedral iodide molybdenum clusters, pyridine",
author = "Marchuk, {Margarita V.} and Vorotnikov, {Yuri A.} and Ivanov, {Anton A.} and Eltsov, {Ilia V.} and Kuratieva, {Natalia V.} and Shestopalov, {Michael A.}",
note = "Funding Information: This research was funded by The Council for Grants of the President of the Russian Federation, grant number MK-87.2022.1.3. YAV thanks The Council for Grants of the President of the Russian Federation (scholarship № SP-3328.2021.1). NIIC team thanks the Ministry of Science and Higher Education of the Russian Federation (№ 121031700321-3 and 121031700313-8). Publisher Copyright: {\textcopyright} 2022 by the authors.",
year = "2022",
month = oct,
doi = "10.3390/sym14102117",
language = "English",
volume = "14",
journal = "Symmetry",
issn = "2073-8994",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "10",

}

RIS

TY - JOUR

T1 - A Neutral Heteroleptic Molybdenum Cluster trans-[{Mo6I8}(py)2I4]

AU - Marchuk, Margarita V.

AU - Vorotnikov, Yuri A.

AU - Ivanov, Anton A.

AU - Eltsov, Ilia V.

AU - Kuratieva, Natalia V.

AU - Shestopalov, Michael A.

N1 - Funding Information: This research was funded by The Council for Grants of the President of the Russian Federation, grant number MK-87.2022.1.3. YAV thanks The Council for Grants of the President of the Russian Federation (scholarship № SP-3328.2021.1). NIIC team thanks the Ministry of Science and Higher Education of the Russian Federation (№ 121031700321-3 and 121031700313-8). Publisher Copyright: © 2022 by the authors.

PY - 2022/10

Y1 - 2022/10

N2 - Despite that the chemistry of octahedral cluster complexes has been actively developed recently, there are still a lot of unexplored areas. For example, to date, only a few halide M6-clusters with N-heterocycles are known. Here, we obtained an apically heteroleptic octahedral iodide molybdenum cluster complex with pyridine ligands—trans-[{Mo6I8}(py)2I4] by the direct substitution of iodide apical ligands of [{Mo6I8}I6]2– in a pyridine solution. The compound co-crystalized with a monosubstituted form [{Mo6I8}(py)I5]– in the ratio of 1:4, and thus, can be described by the formula (pyH)0.2[{Mo6I8}(py)1.8I4.2]·1.8py. The composition was studied using XRPD, elemental analyses, and 1H-NMR and IR spectroscopies. According to the absorption and luminescence data, the partial substitution of apical ligands weakly affects optical properties.

AB - Despite that the chemistry of octahedral cluster complexes has been actively developed recently, there are still a lot of unexplored areas. For example, to date, only a few halide M6-clusters with N-heterocycles are known. Here, we obtained an apically heteroleptic octahedral iodide molybdenum cluster complex with pyridine ligands—trans-[{Mo6I8}(py)2I4] by the direct substitution of iodide apical ligands of [{Mo6I8}I6]2– in a pyridine solution. The compound co-crystalized with a monosubstituted form [{Mo6I8}(py)I5]– in the ratio of 1:4, and thus, can be described by the formula (pyH)0.2[{Mo6I8}(py)1.8I4.2]·1.8py. The composition was studied using XRPD, elemental analyses, and 1H-NMR and IR spectroscopies. According to the absorption and luminescence data, the partial substitution of apical ligands weakly affects optical properties.

KW - absorption

KW - crystal structure

KW - luminescence

KW - octahedral iodide molybdenum clusters

KW - pyridine

UR - http://www.scopus.com/inward/record.url?scp=85140888967&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/18256439-0eb0-3cd8-a04c-5b4d67620921/

U2 - 10.3390/sym14102117

DO - 10.3390/sym14102117

M3 - Article

AN - SCOPUS:85140888967

VL - 14

JO - Symmetry

JF - Symmetry

SN - 2073-8994

IS - 10

M1 - 2117

ER -

ID: 38661183