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A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics. / Sinko, Anton; Solyankin, Peter; Kargovsky, Aleksey et al.

In: Scientific Reports, Vol. 11, No. 1, 23433, 12.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Sinko, A, Solyankin, P, Kargovsky, A, Manomenova, V, Rudneva, E, Kozlova, N, Sorokina, N, Minakov, F, Kuznetsov, S, Nikolaev, N, Surovtsev, N, Ozheredov, I, Voloshin, A & Shkurinov, A 2021, 'A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics', Scientific Reports, vol. 11, no. 1, 23433. https://doi.org/10.1038/s41598-021-02862-3

APA

Sinko, A., Solyankin, P., Kargovsky, A., Manomenova, V., Rudneva, E., Kozlova, N., Sorokina, N., Minakov, F., Kuznetsov, S., Nikolaev, N., Surovtsev, N., Ozheredov, I., Voloshin, A., & Shkurinov, A. (2021). A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics. Scientific Reports, 11(1), [23433]. https://doi.org/10.1038/s41598-021-02862-3

Vancouver

Sinko A, Solyankin P, Kargovsky A, Manomenova V, Rudneva E, Kozlova N et al. A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics. Scientific Reports. 2021 Dec;11(1):23433. doi: 10.1038/s41598-021-02862-3

Author

Sinko, Anton ; Solyankin, Peter ; Kargovsky, Aleksey et al. / A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics. In: Scientific Reports. 2021 ; Vol. 11, No. 1.

BibTeX

@article{2044b35f89a94085b08cb540b0c1fac0,
title = "A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics",
abstract = "In this paper we describe the properties of the crystal of guanylurea hydrogen phosphate (NH2)2CNHCO(NH2)H2PO3 (GUHP) and propose its application in terahertz photonics and optoelectronics. GUHP crystal has a wide window of transparency and a high optical threshold in the visible and NIR spectral regions and narrow absorption bands in the terahertz frequency range. The spectral characteristics of absorption and refraction in the THz range were found to be strongly dependent on crystal temperature and orientation. Computer simulations made it possible to link the nature of the resonant response of the medium at THz frequencies with the molecular structure of the crystal, in particular, with intermolecular hydrogen bonds and the layered structure of the lattice. The possibility of application of the crystal under study for the conversion of femtosecond laser radiation from visible an NIR to terahertz range was demonstrated. It was shown that dispersion properties of the crystal allow the generation of narrow band terahertz radiation, whose spectral properties are determined by conditions close to phase matching. The properties of the generated terahertz radiation under various temperatures suggest the possibility of phonon mechanism of enhancement for nonlinear susceptibility of the second order.",
author = "Anton Sinko and Peter Solyankin and Aleksey Kargovsky and Vera Manomenova and Elena Rudneva and Natalia Kozlova and Natalia Sorokina and Fedor Minakov and Sergei Kuznetsov and Nazar Nikolaev and Nikolay Surovtsev and Ilya Ozheredov and Alexey Voloshin and Alexander Shkurinov",
note = "Funding Information: The authors express gratitude to J.-L.Coutaz for reading the manuscript and useful remarks, to M.Bernier for fruitfull discussions. This work was supported in part by the Russian Foundation for Basic Research (Projects 18-29-20104 & 20-32-90234), by the Ministry of Science and Higher Education of the Russian Federation (Project 0748-2020-0012), by the Interdisciplinary Scientific and Educational School of Moscow University “Photonic and Quantum Technologies. Digital Medicine” and by the Ministry of Science and Higher Education within the State assignment FSRC “Crystallography and Photonics” RAS. The computational research was carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University. F. Minakov, N. Nikolaev and N. Surovtsev acknowledge the Ministry of Science and Higher Education of the Russian Federation (Project 121032400052-6) for support in the development of methods for polarization terahertz spectroscopy and Raman spectroscopy used to study the properties of the GUHP crystal. S. Kuznetsov acknowledges the Ministry of Science and Higher Education of the Russian Federation (Project 075-15-2020-797) for support in the development of THz polarizers. Publisher Copyright: {\textcopyright} 2021, The Author(s).",
year = "2021",
month = dec,
doi = "10.1038/s41598-021-02862-3",
language = "English",
volume = "11",
journal = "Scientific Reports",
issn = "2045-2322",
publisher = "Nature Publishing Group",
number = "1",

}

RIS

TY - JOUR

T1 - A monoclinic semiorganic molecular crystal GUHP for terahertz photonics and optoelectronics

AU - Sinko, Anton

AU - Solyankin, Peter

AU - Kargovsky, Aleksey

AU - Manomenova, Vera

AU - Rudneva, Elena

AU - Kozlova, Natalia

AU - Sorokina, Natalia

AU - Minakov, Fedor

AU - Kuznetsov, Sergei

AU - Nikolaev, Nazar

AU - Surovtsev, Nikolay

AU - Ozheredov, Ilya

AU - Voloshin, Alexey

AU - Shkurinov, Alexander

N1 - Funding Information: The authors express gratitude to J.-L.Coutaz for reading the manuscript and useful remarks, to M.Bernier for fruitfull discussions. This work was supported in part by the Russian Foundation for Basic Research (Projects 18-29-20104 & 20-32-90234), by the Ministry of Science and Higher Education of the Russian Federation (Project 0748-2020-0012), by the Interdisciplinary Scientific and Educational School of Moscow University “Photonic and Quantum Technologies. Digital Medicine” and by the Ministry of Science and Higher Education within the State assignment FSRC “Crystallography and Photonics” RAS. The computational research was carried out using the equipment of the shared research facilities of HPC computing resources at Lomonosov Moscow State University. F. Minakov, N. Nikolaev and N. Surovtsev acknowledge the Ministry of Science and Higher Education of the Russian Federation (Project 121032400052-6) for support in the development of methods for polarization terahertz spectroscopy and Raman spectroscopy used to study the properties of the GUHP crystal. S. Kuznetsov acknowledges the Ministry of Science and Higher Education of the Russian Federation (Project 075-15-2020-797) for support in the development of THz polarizers. Publisher Copyright: © 2021, The Author(s).

PY - 2021/12

Y1 - 2021/12

N2 - In this paper we describe the properties of the crystal of guanylurea hydrogen phosphate (NH2)2CNHCO(NH2)H2PO3 (GUHP) and propose its application in terahertz photonics and optoelectronics. GUHP crystal has a wide window of transparency and a high optical threshold in the visible and NIR spectral regions and narrow absorption bands in the terahertz frequency range. The spectral characteristics of absorption and refraction in the THz range were found to be strongly dependent on crystal temperature and orientation. Computer simulations made it possible to link the nature of the resonant response of the medium at THz frequencies with the molecular structure of the crystal, in particular, with intermolecular hydrogen bonds and the layered structure of the lattice. The possibility of application of the crystal under study for the conversion of femtosecond laser radiation from visible an NIR to terahertz range was demonstrated. It was shown that dispersion properties of the crystal allow the generation of narrow band terahertz radiation, whose spectral properties are determined by conditions close to phase matching. The properties of the generated terahertz radiation under various temperatures suggest the possibility of phonon mechanism of enhancement for nonlinear susceptibility of the second order.

AB - In this paper we describe the properties of the crystal of guanylurea hydrogen phosphate (NH2)2CNHCO(NH2)H2PO3 (GUHP) and propose its application in terahertz photonics and optoelectronics. GUHP crystal has a wide window of transparency and a high optical threshold in the visible and NIR spectral regions and narrow absorption bands in the terahertz frequency range. The spectral characteristics of absorption and refraction in the THz range were found to be strongly dependent on crystal temperature and orientation. Computer simulations made it possible to link the nature of the resonant response of the medium at THz frequencies with the molecular structure of the crystal, in particular, with intermolecular hydrogen bonds and the layered structure of the lattice. The possibility of application of the crystal under study for the conversion of femtosecond laser radiation from visible an NIR to terahertz range was demonstrated. It was shown that dispersion properties of the crystal allow the generation of narrow band terahertz radiation, whose spectral properties are determined by conditions close to phase matching. The properties of the generated terahertz radiation under various temperatures suggest the possibility of phonon mechanism of enhancement for nonlinear susceptibility of the second order.

UR - http://www.scopus.com/inward/record.url?scp=85120906863&partnerID=8YFLogxK

U2 - 10.1038/s41598-021-02862-3

DO - 10.1038/s41598-021-02862-3

M3 - Article

C2 - 34873239

AN - SCOPUS:85120906863

VL - 11

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

IS - 1

M1 - 23433

ER -

ID: 34968978