Standard

A : Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement. / Matveeva, Svetlana G.; Shushakov, Anton A.; Pozdnyakov, Ivan P. et al.

In: Photochemical and Photobiological Sciences, Vol. 17, No. 9, 09.2018, p. 1222-1228.

Research output: Contribution to journal › Article › peer-review

Harvard

Matveeva, SG, Shushakov, AA, Pozdnyakov, IP, Grivin, VP, Plyusnin, VF, Vasilchenko, DB, Zadesenets, AV, Melnikov, AA, Chekalin, SV & Glebov, EM 2018, 'A: Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement', Photochemical and Photobiological Sciences, vol. 17, no. 9, pp. 1222-1228. https://doi.org/10.1039/c8pp00232k

APA

Matveeva, S. G., Shushakov, A. A., Pozdnyakov, I. P., Grivin, V. P., Plyusnin, V. F., Vasilchenko, D. B., Zadesenets, A. V., Melnikov, A. A., Chekalin, S. V., & Glebov, E. M. (2018). A: Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement. Photochemical and Photobiological Sciences, 17(9), 1222-1228. https://doi.org/10.1039/c8pp00232k

Vancouver

Matveeva SG, Shushakov AA, Pozdnyakov IP, Grivin VP, Plyusnin VF, Vasilchenko DB et al. A: Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement. Photochemical and Photobiological Sciences. 2018 Sept;17(9):1222-1228. doi: 10.1039/c8pp00232k

Author

Matveeva, Svetlana G. ; Shushakov, Anton A. ; Pozdnyakov, Ivan P. et al. / A : Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement. In: Photochemical and Photobiological Sciences. 2018 ; Vol. 17, No. 9. pp. 1222-1228.

BibTeX

@article{76d3bb68fa224b60a5fd52c1dcef96c3,
title = "A: Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement",
abstract = "It is known that both cis,fac-[RuCl2(DMSO)3(H2O)] (1a) and trans,cis,cis-[RuCl2(DMSO)2(H2O)2] (2a) complexes, which are formed on the dissolution of trans and cis-isomers of [RuCl2(DMSO)4] in water, demonstrate light-induced anticancer activity. The first stage of 1a photochemistry is its transformation to 2a occurring with a rather high quantum yield, 0.64 ± 0.17. The mechanism of the 1a → 2a phototransformation was studied by means of nanosecond laser flash photolysis and ultrafast pump-probe spectroscopy. The reaction occurs in the picosecond time range via the formation and decay of two successive intermediates interpreted as Ru(ii) complexes with different sets of ligands. A tentative mechanism of phototransformation is proposed.",
keywords = "PUMP-PROBE SPECTROSCOPY, AQUEOUS-SOLUTIONS, PHOTODYNAMIC THERAPY, EXCITED-STATES, DYNAMICS, SULFOXIDE)RUTHENIUM(II), RUTHENIUM(III), PHOTOPHYSICS, CR(ACAC)(3)",
author = "Matveeva, {Svetlana G.} and Shushakov, {Anton A.} and Pozdnyakov, {Ivan P.} and Grivin, {Vjacheslav P.} and Plyusnin, {Victor F.} and Vasilchenko, {Danila B.} and Zadesenets, {Andrei V.} and Melnikov, {Alexei A.} and Chekalin, {Sergei V.} and Glebov, {Evgeni M.}",
year = "2018",
month = sep,
doi = "10.1039/c8pp00232k",
language = "English",
volume = "17",
pages = "1222--1228",
journal = "Photochemical and Photobiological Sciences",
issn = "1474-905X",
publisher = "Royal Society of Chemistry",
number = "9",

}

RIS

TY - JOUR

T1 - A

T2 - Cis, fac -[RuCl2(DMSO)3(H2O)] complex exhibits ultrafast photochemical aquation/rearrangement

AU - Matveeva, Svetlana G.

AU - Shushakov, Anton A.

AU - Pozdnyakov, Ivan P.

AU - Grivin, Vjacheslav P.

AU - Plyusnin, Victor F.

AU - Vasilchenko, Danila B.

AU - Zadesenets, Andrei V.

AU - Melnikov, Alexei A.

AU - Chekalin, Sergei V.

AU - Glebov, Evgeni M.

PY - 2018/9

Y1 - 2018/9

N2 - It is known that both cis,fac-[RuCl2(DMSO)3(H2O)] (1a) and trans,cis,cis-[RuCl2(DMSO)2(H2O)2] (2a) complexes, which are formed on the dissolution of trans and cis-isomers of [RuCl2(DMSO)4] in water, demonstrate light-induced anticancer activity. The first stage of 1a photochemistry is its transformation to 2a occurring with a rather high quantum yield, 0.64 ± 0.17. The mechanism of the 1a → 2a phototransformation was studied by means of nanosecond laser flash photolysis and ultrafast pump-probe spectroscopy. The reaction occurs in the picosecond time range via the formation and decay of two successive intermediates interpreted as Ru(ii) complexes with different sets of ligands. A tentative mechanism of phototransformation is proposed.

AB - It is known that both cis,fac-[RuCl2(DMSO)3(H2O)] (1a) and trans,cis,cis-[RuCl2(DMSO)2(H2O)2] (2a) complexes, which are formed on the dissolution of trans and cis-isomers of [RuCl2(DMSO)4] in water, demonstrate light-induced anticancer activity. The first stage of 1a photochemistry is its transformation to 2a occurring with a rather high quantum yield, 0.64 ± 0.17. The mechanism of the 1a → 2a phototransformation was studied by means of nanosecond laser flash photolysis and ultrafast pump-probe spectroscopy. The reaction occurs in the picosecond time range via the formation and decay of two successive intermediates interpreted as Ru(ii) complexes with different sets of ligands. A tentative mechanism of phototransformation is proposed.

KW - PUMP-PROBE SPECTROSCOPY

KW - AQUEOUS-SOLUTIONS

KW - PHOTODYNAMIC THERAPY

KW - EXCITED-STATES

KW - DYNAMICS

KW - SULFOXIDE)RUTHENIUM(II)

KW - RUTHENIUM(III)

KW - PHOTOPHYSICS

KW - CR(ACAC)(3)

UR - http://www.scopus.com/inward/record.url?scp=85053532962&partnerID=8YFLogxK

U2 - 10.1039/c8pp00232k

DO - 10.1039/c8pp00232k

M3 - Article

C2 - 30070288

AN - SCOPUS:85053532962

VL - 17

SP - 1222

EP - 1228

JO - Photochemical and Photobiological Sciences

JF - Photochemical and Photobiological Sciences

SN - 1474-905X

IS - 9

ER -

ID: 16631772