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2-Imidazoline Nitroxide Derivatives of Cymantrene. / Maryunina, Kseniya; Letyagin, Gleb; Romanenko, Galina et al.

In: Molecules (Basel, Switzerland), Vol. 27, No. 21, 7545, 03.11.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Maryunina, K, Letyagin, G, Romanenko, G, Bogomyakov, A, Morozov, V, Tumanov, S, Veber, S, Fedin, M, Saverina, E, Syroeshkin, M, Egorov, M & Ovcharenko, V 2022, '2-Imidazoline Nitroxide Derivatives of Cymantrene', Molecules (Basel, Switzerland), vol. 27, no. 21, 7545. https://doi.org/10.3390/molecules27217545

APA

Maryunina, K., Letyagin, G., Romanenko, G., Bogomyakov, A., Morozov, V., Tumanov, S., Veber, S., Fedin, M., Saverina, E., Syroeshkin, M., Egorov, M., & Ovcharenko, V. (2022). 2-Imidazoline Nitroxide Derivatives of Cymantrene. Molecules (Basel, Switzerland), 27(21), [7545]. https://doi.org/10.3390/molecules27217545

Vancouver

Maryunina K, Letyagin G, Romanenko G, Bogomyakov A, Morozov V, Tumanov S et al. 2-Imidazoline Nitroxide Derivatives of Cymantrene. Molecules (Basel, Switzerland). 2022 Nov 3;27(21):7545. doi: 10.3390/molecules27217545

Author

Maryunina, Kseniya ; Letyagin, Gleb ; Romanenko, Galina et al. / 2-Imidazoline Nitroxide Derivatives of Cymantrene. In: Molecules (Basel, Switzerland). 2022 ; Vol. 27, No. 21.

BibTeX

@article{eadcb2ac351640d483519290649ad59b,
title = "2-Imidazoline Nitroxide Derivatives of Cymantrene",
abstract = "The 2-imidazoline nitroxide derivatives of cymantrene-2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (NNMn) and 2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (INMn) were synthesized. It was shown that NNMn and INMn exhibit a sufficiently high kinetic stability both in solids and in solutions under normal conditions. Their structural characteristics, magnetic properties and electrochemical behavior are close to Re(I) analogs. This opens the prospect of using paramagnetic cymantrenes as prototypes in the design of Re(I) half-sandwiched derivatives for theranostics, where therapy is combined with diagnostics by magnetic resonance imaging due to the contrast properties of nitroxide radicals.",
keywords = "cymantrene, manganeseorganic, nitroxide, paramagnets",
author = "Kseniya Maryunina and Gleb Letyagin and Galina Romanenko and Artem Bogomyakov and Vitaly Morozov and Sergey Tumanov and Sergey Veber and Matvey Fedin and Evgeniya Saverina and Mikhail Syroeshkin and Mikhail Egorov and Victor Ovcharenko",
note = "Publisher Copyright: {\textcopyright} 2022 by the authors.",
year = "2022",
month = nov,
day = "3",
doi = "10.3390/molecules27217545",
language = "English",
volume = "27",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "21",

}

RIS

TY - JOUR

T1 - 2-Imidazoline Nitroxide Derivatives of Cymantrene

AU - Maryunina, Kseniya

AU - Letyagin, Gleb

AU - Romanenko, Galina

AU - Bogomyakov, Artem

AU - Morozov, Vitaly

AU - Tumanov, Sergey

AU - Veber, Sergey

AU - Fedin, Matvey

AU - Saverina, Evgeniya

AU - Syroeshkin, Mikhail

AU - Egorov, Mikhail

AU - Ovcharenko, Victor

N1 - Publisher Copyright: © 2022 by the authors.

PY - 2022/11/3

Y1 - 2022/11/3

N2 - The 2-imidazoline nitroxide derivatives of cymantrene-2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (NNMn) and 2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (INMn) were synthesized. It was shown that NNMn and INMn exhibit a sufficiently high kinetic stability both in solids and in solutions under normal conditions. Their structural characteristics, magnetic properties and electrochemical behavior are close to Re(I) analogs. This opens the prospect of using paramagnetic cymantrenes as prototypes in the design of Re(I) half-sandwiched derivatives for theranostics, where therapy is combined with diagnostics by magnetic resonance imaging due to the contrast properties of nitroxide radicals.

AB - The 2-imidazoline nitroxide derivatives of cymantrene-2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (NNMn) and 2-(η5-cyclopentadienyl)tricarbonylmanganese(I)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl (INMn) were synthesized. It was shown that NNMn and INMn exhibit a sufficiently high kinetic stability both in solids and in solutions under normal conditions. Their structural characteristics, magnetic properties and electrochemical behavior are close to Re(I) analogs. This opens the prospect of using paramagnetic cymantrenes as prototypes in the design of Re(I) half-sandwiched derivatives for theranostics, where therapy is combined with diagnostics by magnetic resonance imaging due to the contrast properties of nitroxide radicals.

KW - cymantrene

KW - manganeseorganic

KW - nitroxide

KW - paramagnets

UR - http://www.scopus.com/inward/record.url?scp=85141632629&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/f6788c85-11ad-3dc5-a604-4deeb7a8055a/

U2 - 10.3390/molecules27217545

DO - 10.3390/molecules27217545

M3 - Article

C2 - 36364372

AN - SCOPUS:85141632629

VL - 27

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 21

M1 - 7545

ER -

ID: 39329965