Standard

(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one. / Ardashov, Oleg V.; Korchagina, Dina V.; Bagryanskaya, Irina Yu et al.

In: MolBank, Vol. 2022, No. 4, M1465, 01.12.2022.

Research output: Contribution to journal › Article › peer-review

Harvard

Ardashov, OV, Korchagina, DV, Bagryanskaya, IY, Volcho, KP & Salakhutdinov, NF 2022, '(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one', MolBank, vol. 2022, no. 4, M1465. https://doi.org/10.3390/M1465

APA

Ardashov, O. V., Korchagina, D. V., Bagryanskaya, I. Y., Volcho, K. P., & Salakhutdinov, N. F. (2022). (1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one. MolBank, 2022(4), [M1465]. https://doi.org/10.3390/M1465

Vancouver

Ardashov OV, Korchagina DV, Bagryanskaya IY, Volcho KP, Salakhutdinov NF. (1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one. MolBank. 2022 Dec 1;2022(4):M1465. doi: 10.3390/M1465

Author

Ardashov, Oleg V. ; Korchagina, Dina V. ; Bagryanskaya, Irina Yu et al. / (1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one. In: MolBank. 2022 ; Vol. 2022, No. 4.

BibTeX

@article{7fb8a9cc084445818d07b6a5e9e7951e,
title = "(1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one",
abstract = "A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.",
keywords = "Michael addition, dimerization, extended enolate, verbenone",
author = "Ardashov, {Oleg V.} and Korchagina, {Dina V.} and Bagryanskaya, {Irina Yu} and Volcho, {Konstantin P.} and Salakhutdinov, {Nariman F.}",
note = "Funding: The current work was financially supported by the Russian Foundation for Basic Research (Grant No 19-29-04011).",
year = "2022",
month = dec,
day = "1",
doi = "10.3390/M1465",
language = "English",
volume = "2022",
journal = "MolBank",
issn = "1422-8599",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "4",

}

RIS

TY - JOUR

T1 - (1S,5R)-6,6-Dimethyl-4-(((1S,2S,5S)-2,6,6-trimethyl-4-oxobicyclo[3.1.1]heptan-2-yl)methyl)bicyclo[3.1.1]hept-3-en-2-one

AU - Ardashov, Oleg V.

AU - Korchagina, Dina V.

AU - Bagryanskaya, Irina Yu

AU - Volcho, Konstantin P.

AU - Salakhutdinov, Nariman F.

N1 - Funding: The current work was financially supported by the Russian Foundation for Basic Research (Grant No 19-29-04011).

PY - 2022/12/1

Y1 - 2022/12/1

N2 - A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.

AB - A simple and convenient procedure for the γ, β-dimerization of verbenone was developed. The dimer was obtained during aging with KOH without a solvent. The process proceeds as the formation of the extended enolate of verbenone and its Michael addition to other molecules of verbenone. The product yield was 82% after purification by column chromatography and recrystallization.

KW - Michael addition

KW - dimerization

KW - extended enolate

KW - verbenone

UR - https://www.scopus.com/inward/record.url?eid=2-s2.0-85144684367&partnerID=40&md5=b499369c17848903e4871d1802a3a5aa

UR - https://www.mendeley.com/catalogue/ae4fa48e-dfd1-33a0-83b0-4d1fe056f2e8/

U2 - 10.3390/M1465

DO - 10.3390/M1465

M3 - Article

VL - 2022

JO - MolBank

JF - MolBank

SN - 1422-8599

IS - 4

M1 - M1465

ER -

ID: 44674261