Research output: Contribution to journal › Article › peer-review
1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties. / Shentseva, I. A.; Usol’tsev, A. N.; Korobeinikov, N. A. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 50, No. 10, 10.2024, p. 809-816.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - 1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties
AU - Shentseva, I. A.
AU - Usol’tsev, A. N.
AU - Korobeinikov, N. A.
AU - Adonin, S. A.
N1 - he authors are grateful to the Ministry of Science and Higher Education of the Russian Federation (structural characterization of samples, state assignment no. 121031700313-8). This work was supported by the Russian Science Foundation, project no. 23-73-10054.
PY - 2024/10
Y1 - 2024/10
N2 - Abstract: The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI4]} (I) and (3-Br-1-MePy){[SbI4]} (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.
AB - Abstract: The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI4]} (I) and (3-Br-1-MePy){[SbI4]} (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.
KW - XRD
KW - antimony
KW - complexes
KW - halide complexes
KW - noncovalent interactions
UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85211316023&origin=inward&txGid=0e9e96716ed5720532016154498d6f58
UR - https://www.mendeley.com/catalogue/ff805f00-3a46-3be9-baf5-2a216b6dd8b0/
U2 - 10.1134/S1070328424600700
DO - 10.1134/S1070328424600700
M3 - Article
VL - 50
SP - 809
EP - 816
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 10
ER -
ID: 61285322