Standard

1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]. / Mikhaylov, M. a.; Berezin, A. s.; Sukhikh, T. s. et al.

In: Journal of Structural Chemistry, Vol. 66, No. 1, 12.02.2025, p. 87-96.

Research output: Contribution to journal › Article › peer-review

Harvard

Mikhaylov, MA, Berezin, AS, Sukhikh, TS, Sheven’, DG, Kompankov, NB, Sokolov, MN & Tagiltsev, KA 2025, '1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]', Journal of Structural Chemistry, vol. 66, no. 1, pp. 87-96. https://doi.org/10.1134/S0022476625010081

APA

Mikhaylov, M. A., Berezin, A. S., Sukhikh, T. S., Sheven’, D. G., Kompankov, N. B., Sokolov, M. N., & Tagiltsev, K. A. (2025). 1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]. Journal of Structural Chemistry, 66(1), 87-96. https://doi.org/10.1134/S0022476625010081

Vancouver

Mikhaylov MA, Berezin AS, Sukhikh TS, Sheven’ DG, Kompankov NB, Sokolov MN et al. 1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]. Journal of Structural Chemistry. 2025 Feb 12;66(1):87-96. doi: 10.1134/S0022476625010081

Author

Mikhaylov, M. a. ; Berezin, A. s. ; Sukhikh, T. s. et al. / 1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]. In: Journal of Structural Chemistry. 2025 ; Vol. 66, No. 1. pp. 87-96.

BibTeX

@article{5fbe155a12934c3386d8ae2fb8a41cc4,
title = "1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]",
abstract = "New luminescent cluster complex (Bu4N)2[W6I8(N3C6H4)6] (I) is obtained by the reaction of (Bu4N)2[W6I8(OOCCH3)6] with 1-trimethylsilyl-1,2,3-benzotriazole (Me3Si-N3C6H4) is obtained. The crystal structure is determined for cocrystallizate I with 1,2,3-benzotriazole (Bu4N)2[W6I8(N3C6H4)6]· ·4(N3C6H5) (I·4BTA). According to single crystal X-ray diffraction data, tungsten atoms of the {W6I8}4+ cluster core are monodentate coordinated by N1 atoms of 1,2,3-benzotriazolate ligands (average W–N distance 2.20 {\AA}). For the powder sample of I bright phosphorescence is revealed with the emission maximum at 640 nm, φ = 24%, τ = 266 µs (in the air atmosphere). Complex I is characterized by electrospray mass spectrometry, proton magnetic resonance, C, H, N elemental analysis, and IR spectroscopy. ",
keywords = "benzotriazolate complexes, clusters, iodides, luminescence, nuclear magnetic resonance, single crystal X-ray diffraction analysis, trimethylsilyl derivatives, tungsten",
author = "Mikhaylov, {M. a.} and Berezin, {A. s.} and Sukhikh, {T. s.} and Sheven{\textquoteright}, {D. g.} and Kompankov, {N. b.} and Sokolov, {M. n.} and Tagiltsev, {K. a.}",
note = "The work was supported by Russian Science Foundation grant No. 24-23-00397. 1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6] / M. A. Mikhaylov, A. S. Berezin, T. S. Sukhikh [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 1. – P. 87-96. – DOI 10.1134/S0022476625010081.",
year = "2025",
month = feb,
day = "12",
doi = "10.1134/S0022476625010081",
language = "English",
volume = "66",
pages = "87--96",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer",
number = "1",

}

RIS

TY - JOUR

T1 - 1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6]

AU - Mikhaylov, M. a.

AU - Berezin, A. s.

AU - Sukhikh, T. s.

AU - Sheven’, D. g.

AU - Kompankov, N. b.

AU - Sokolov, M. n.

AU - Tagiltsev, K. a.

N1 - The work was supported by Russian Science Foundation grant No. 24-23-00397. 1,2,3-Benzotriazolate Cluster Complex (Bu4N)2[W6I8(N3C6H4)6] / M. A. Mikhaylov, A. S. Berezin, T. S. Sukhikh [et al.] // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 1. – P. 87-96. – DOI 10.1134/S0022476625010081.

PY - 2025/2/12

Y1 - 2025/2/12

N2 - New luminescent cluster complex (Bu4N)2[W6I8(N3C6H4)6] (I) is obtained by the reaction of (Bu4N)2[W6I8(OOCCH3)6] with 1-trimethylsilyl-1,2,3-benzotriazole (Me3Si-N3C6H4) is obtained. The crystal structure is determined for cocrystallizate I with 1,2,3-benzotriazole (Bu4N)2[W6I8(N3C6H4)6]· ·4(N3C6H5) (I·4BTA). According to single crystal X-ray diffraction data, tungsten atoms of the {W6I8}4+ cluster core are monodentate coordinated by N1 atoms of 1,2,3-benzotriazolate ligands (average W–N distance 2.20 Å). For the powder sample of I bright phosphorescence is revealed with the emission maximum at 640 nm, φ = 24%, τ = 266 µs (in the air atmosphere). Complex I is characterized by electrospray mass spectrometry, proton magnetic resonance, C, H, N elemental analysis, and IR spectroscopy.

AB - New luminescent cluster complex (Bu4N)2[W6I8(N3C6H4)6] (I) is obtained by the reaction of (Bu4N)2[W6I8(OOCCH3)6] with 1-trimethylsilyl-1,2,3-benzotriazole (Me3Si-N3C6H4) is obtained. The crystal structure is determined for cocrystallizate I with 1,2,3-benzotriazole (Bu4N)2[W6I8(N3C6H4)6]· ·4(N3C6H5) (I·4BTA). According to single crystal X-ray diffraction data, tungsten atoms of the {W6I8}4+ cluster core are monodentate coordinated by N1 atoms of 1,2,3-benzotriazolate ligands (average W–N distance 2.20 Å). For the powder sample of I bright phosphorescence is revealed with the emission maximum at 640 nm, φ = 24%, τ = 266 µs (in the air atmosphere). Complex I is characterized by electrospray mass spectrometry, proton magnetic resonance, C, H, N elemental analysis, and IR spectroscopy.

KW - benzotriazolate complexes

KW - clusters

KW - iodides

KW - luminescence

KW - nuclear magnetic resonance

KW - single crystal X-ray diffraction analysis

KW - trimethylsilyl derivatives

KW - tungsten

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85218815492&origin=inward&txGid=9fe2b166e219d4bc43527f93fc34a9ce

UR - https://www.mendeley.com/catalogue/be0638ab-7872-3540-a2a0-7b6c69e7bf5c/

UR - https://elibrary.ru/item.asp?id=80320812

U2 - 10.1134/S0022476625010081

DO - 10.1134/S0022476625010081

M3 - Article

VL - 66

SP - 87

EP - 96

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 64947193